The Synthesis and X-ray Structure of the First Cobalt Carbonyl-NHC Dimer. Implications for the Use of NHCs in Hydroformylation Catalysis

H van Rensburg; RP Tooze; DF Foster; Alexandra Martha Zoya Slawin

doi:10.1021/ic049917f

The Synthesis and X-ray Structure of the First Cobalt Carbonyl-NHC Dimer. Implications for the Use of NHCs in Hydroformylation Catalysis

H van Rensburg, RP Tooze, DF Foster, Alexandra Martha Zoya Slawin

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis, X-ray structure, and catalytic properties of the first cobalt carbonyl dimer supported by a N-heterocyclic carbene ligand Co-2(CO)(6)(IMes)(2) {IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene} is reported.

Original language	English
Pages (from-to)	2468-2470
Number of pages	3
Journal	Inorganic Chemistry
Volume	43
Issue number	8
DOIs	https://doi.org/10.1021/ic049917f
Publication status	Published - 19 Apr 2004

Keywords

N-HETEROCYCLIC CARBENES
COMPLEXES
DERIVATIVES
REDUCTION
RHODIUM
OLEFINS

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10.1021/ic049917f

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title = "The Synthesis and X-ray Structure of the First Cobalt Carbonyl-NHC Dimer. Implications for the Use of NHCs in Hydroformylation Catalysis",

abstract = "The synthesis, X-ray structure, and catalytic properties of the first cobalt carbonyl dimer supported by a N-heterocyclic carbene ligand Co-2(CO)(6)(IMes)(2) {IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene} is reported.",

keywords = "N-HETEROCYCLIC CARBENES, COMPLEXES, DERIVATIVES, REDUCTION, RHODIUM, OLEFINS",

author = "{van Rensburg}, H and RP Tooze and DF Foster and Slawin, {Alexandra Martha Zoya}",

year = "2004",

month = apr,

day = "19",

doi = "10.1021/ic049917f",

language = "English",

volume = "43",

pages = "2468--2470",

journal = "Inorganic Chemistry",

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T1 - The Synthesis and X-ray Structure of the First Cobalt Carbonyl-NHC Dimer. Implications for the Use of NHCs in Hydroformylation Catalysis

AU - van Rensburg, H

AU - Tooze, RP

AU - Foster, DF

AU - Slawin, Alexandra Martha Zoya

PY - 2004/4/19

Y1 - 2004/4/19

N2 - The synthesis, X-ray structure, and catalytic properties of the first cobalt carbonyl dimer supported by a N-heterocyclic carbene ligand Co-2(CO)(6)(IMes)(2) {IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene} is reported.

AB - The synthesis, X-ray structure, and catalytic properties of the first cobalt carbonyl dimer supported by a N-heterocyclic carbene ligand Co-2(CO)(6)(IMes)(2) {IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene} is reported.

KW - N-HETEROCYCLIC CARBENES

KW - COMPLEXES

KW - DERIVATIVES

KW - REDUCTION

KW - RHODIUM

KW - OLEFINS

UR - http://www.scopus.com/inward/record.url?scp=6044225961&partnerID=8YFLogxK

UR - http://pubs3.acs.org/acs/journals/doilookup?in_doi=10.1021/ic049917f

U2 - 10.1021/ic049917f

DO - 10.1021/ic049917f

M3 - Article

SN - 0020-1669

VL - 43

SP - 2468

EP - 2470

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 8

ER -

The Synthesis and X-ray Structure of the First Cobalt Carbonyl-NHC Dimer. Implications for the Use of NHCs in Hydroformylation Catalysis

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Keywords

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