Projects per year
Abstract
N-Heterocyclic carbenes (NHCs) have been shown to be useful ligands for the Suzuki-Miyaura cross-coupling at low catalyst loadings. We now report that the commercially available and air-stable [Pd(IPr)(cin)Cl] pre-catalyst permits the formation of various functionalized biaryls from aryl chlorides and boronic acids (37 examples) under very mild conditions using a mixture of ethanol/water as solvent and an inorganic base.
Original language | English |
---|---|
Pages (from-to) | 1920-1924 |
Number of pages | 5 |
Journal | European Journal of Organic Chemistry |
Early online date | 18 Feb 2015 |
DOIs | |
Publication status | Published - 2015 |
Keywords
- Catalysis
- Cross-coupling
- NHC
- Palladium
- Suzuki-Miyaura
Fingerprint
Dive into the research topics of 'The Suzuki-Miyaura reaction performed using a palladium-N-Heterocyclic carbene catalyst and a weak inorganic base'. Together they form a unique fingerprint.Projects
- 2 Finished
-
LSI Collaborative Project: SYNFLOW: EU FP7 Collaborative Project 'SYNFLOW'
Nolan, S. P. (PI) & Cole-Hamilton, D. J. (CoI)
1/09/10 → 31/08/14
Project: Standard
-
FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis
Nolan, S. P. (PI)
1/01/09 → 31/12/14
Project: Standard