TY - GEN
T1 - The structure of poly(ethylene oxide)8: NaBPh4 from a single crystal oligomer and polycrystalline polymer
AU - Staunton, E
AU - Christie, Alasdair Mccall
AU - Andreev, Yuri Georgievich
AU - Slawin, Alexandra Martha Zoya
AU - Bruce, Peter George
N1 - Chem Commun (Camb)
PY - 2004/1/21
Y1 - 2004/1/21
N2 - We show that the structure of a polymer electrolyte may be solved by growing single crystals of an oligomeric (short chain) complex which provided an adequate starting model for refinement of the equivalent polymeric structure using powder diffraction: the efficacy of this method has been demonstrated by determining for the first time the structure of an 8 : 1 complex, poly(ethylene oxide)(8) : NaBPh4.
AB - We show that the structure of a polymer electrolyte may be solved by growing single crystals of an oligomeric (short chain) complex which provided an adequate starting model for refinement of the equivalent polymeric structure using powder diffraction: the efficacy of this method has been demonstrated by determining for the first time the structure of an 8 : 1 complex, poly(ethylene oxide)(8) : NaBPh4.
KW - POWDER-DIFFRACTION DATA
KW - MONTE-CARLO APPROACH
KW - ELECTROLYTE
UR - http://www.scopus.com/inward/record.url?scp=1642520976&partnerID=8YFLogxK
UR - http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=pubmed&dopt=Abstract&list_uids=14737522
U2 - 10.1039/b311800b
DO - 10.1039/b311800b
M3 - Other contribution
VL - 21
ER -