THE SELF-ASSEMBLY OF COMPLEXES WITH [2]PSEUDOROTAXANE SUPERSTRUCTURES

P R  ASHTON; D  PHILP; M V  REDDINGTON; A M Z  SLAWIN; N  SPENCER; J F  STODDART; D J  WILLIAMS

THE SELF-ASSEMBLY OF COMPLEXES WITH [2]PSEUDOROTAXANE SUPERSTRUCTURES

P R ASHTON, D PHILP, M V REDDINGTON, A M Z SLAWIN, N SPENCER, J F STODDART, D J WILLIAMS

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Abstract

The application of X-ray crystallography, mass spectrometry, and NMR and UV-VIS spectroscopy has revealed that bis-p-phenylene-34-crown-10 1 forms strong 1:1 complexes with the 4,4'-bipyridinium dication 3(2+) and two of its derivatives, namely, the dications 4(2+) and 5(2+) in which the substituents on the bipyridine nitrogen atoms are, respectively, 2-hydroxyethyl and 2-(2-hydroxyethoxy)ethyl groups.

Original language	English
Pages (from-to)	1680-1683
Number of pages	4
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	23
Publication status	Published - 1 Dec 1991

Keywords

PARAQUAT

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title = "THE SELF-ASSEMBLY OF COMPLEXES WITH [2]PSEUDOROTAXANE SUPERSTRUCTURES",

abstract = "The application of X-ray crystallography, mass spectrometry, and NMR and UV-VIS spectroscopy has revealed that bis-p-phenylene-34-crown-10 1 forms strong 1:1 complexes with the 4,4'-bipyridinium dication 3(2+) and two of its derivatives, namely, the dications 4(2+) and 5(2+) in which the substituents on the bipyridine nitrogen atoms are, respectively, 2-hydroxyethyl and 2-(2-hydroxyethoxy)ethyl groups.",

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author = "ASHTON, {P R} and D PHILP and REDDINGTON, {M V} and SLAWIN, {A M Z} and N SPENCER and STODDART, {J F} and WILLIAMS, {D J}",

year = "1991",

month = dec,

day = "1",

language = "English",

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journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - THE SELF-ASSEMBLY OF COMPLEXES WITH [2]PSEUDOROTAXANE SUPERSTRUCTURES

AU - ASHTON, P R

AU - PHILP, D

AU - REDDINGTON, M V

AU - SLAWIN, A M Z

AU - SPENCER, N

AU - STODDART, J F

AU - WILLIAMS, D J

PY - 1991/12/1

Y1 - 1991/12/1

N2 - The application of X-ray crystallography, mass spectrometry, and NMR and UV-VIS spectroscopy has revealed that bis-p-phenylene-34-crown-10 1 forms strong 1:1 complexes with the 4,4'-bipyridinium dication 3(2+) and two of its derivatives, namely, the dications 4(2+) and 5(2+) in which the substituents on the bipyridine nitrogen atoms are, respectively, 2-hydroxyethyl and 2-(2-hydroxyethoxy)ethyl groups.

AB - The application of X-ray crystallography, mass spectrometry, and NMR and UV-VIS spectroscopy has revealed that bis-p-phenylene-34-crown-10 1 forms strong 1:1 complexes with the 4,4'-bipyridinium dication 3(2+) and two of its derivatives, namely, the dications 4(2+) and 5(2+) in which the substituents on the bipyridine nitrogen atoms are, respectively, 2-hydroxyethyl and 2-(2-hydroxyethoxy)ethyl groups.

KW - PARAQUAT

M3 - Article

SN - 0022-4936

SP - 1680

EP - 1683

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 23

ER -

THE SELF-ASSEMBLY OF COMPLEXES WITH [2]PSEUDOROTAXANE SUPERSTRUCTURES

Abstract

Keywords

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