TY - JOUR
T1 - The room temperature substitution of n- and iso-perfluoropropyl iodides and n-perfluorobutyl iodide to dimethylplatinum (II) 1,5-cyclooctadiene: The crystal structure of [Pt(C3F7)(2)(COD)]
AU - Thomson, J
AU - Slawin, A M Z
AU - Jain, S L
AU - Lobban, J
PY - 2005/9
Y1 - 2005/9
N2 - The room temperature reaction of dimethylplatinum (II)COD [COD = 1,5-cyclooctadiene] with a molar excess perfluoro-n-propyl iodide produces [Pt(C3F7)(2)(COD)]. Perfluoro-iso-propyl iodide and perfluoro-n-butyl iodide gives the monosubstitute [Pt(i-C3F7)(CH3)(COD)] and [Pt(C4F9)(CH3)(COD)], respectively, consistent with steric hinderance suppressing the second substitution reaction. The crystal structure of [Pt(C3F7)(2)(COD)] reveals square planar geometry about the platinum. (c) 2005 Elsevier B.V. All rights reserved.
AB - The room temperature reaction of dimethylplatinum (II)COD [COD = 1,5-cyclooctadiene] with a molar excess perfluoro-n-propyl iodide produces [Pt(C3F7)(2)(COD)]. Perfluoro-iso-propyl iodide and perfluoro-n-butyl iodide gives the monosubstitute [Pt(i-C3F7)(CH3)(COD)] and [Pt(C4F9)(CH3)(COD)], respectively, consistent with steric hinderance suppressing the second substitution reaction. The crystal structure of [Pt(C3F7)(2)(COD)] reveals square planar geometry about the platinum. (c) 2005 Elsevier B.V. All rights reserved.
KW - perfluoro-n-propyl iodide
KW - pefluoro-iso-propyl iodide
KW - perfluoro-n-butyliodide
KW - dimethylplatinum (II) 1,5-cyclooctadiene
KW - COMPLEXES
UR - https://www.scopus.com/pages/publications/23844454885
U2 - 10.1016/j.inoche.2005.05.022
DO - 10.1016/j.inoche.2005.05.022
M3 - Article
SN - 1387-7003
VL - 8
SP - 782
EP - 784
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
ER -