Abstract
The room temperature reaction of dimethylplatinum (II)COD [COD = 1,5-cyclooctadiene] with a molar excess perfluoro-n-propyl iodide produces [Pt(C3F7)(2)(COD)]. Perfluoro-iso-propyl iodide and perfluoro-n-butyl iodide gives the monosubstitute [Pt(i-C3F7)(CH3)(COD)] and [Pt(C4F9)(CH3)(COD)], respectively, consistent with steric hinderance suppressing the second substitution reaction. The crystal structure of [Pt(C3F7)(2)(COD)] reveals square planar geometry about the platinum. (c) 2005 Elsevier B.V. All rights reserved.
Original language | English |
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Pages (from-to) | 782-784 |
Number of pages | 3 |
Journal | Inorganic Chemistry Communications |
Volume | 8 |
DOIs | |
Publication status | Published - Sept 2005 |
Keywords
- perfluoro-n-propyl iodide
- pefluoro-iso-propyl iodide
- perfluoro-n-butyliodide
- dimethylplatinum (II) 1,5-cyclooctadiene
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