The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

Stephanie Dupuy; Luke Crawford; Michael Buehl; Alexandra M. Z. Slawin; Steven P. Nolan

doi:10.1002/adsc.201200233

The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

Stephanie Dupuy, Luke Crawford, Michael Buehl, Alexandra M. Z. Slawin, Steven P. Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.

Original language	English
Pages (from-to)	2380-2386
Number of pages	7
Journal	Advanced Synthesis & Catalysis
Volume	354
Issue number	13
DOIs	https://doi.org/10.1002/adsc.201200233
Publication status	Published - Sept 2012

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10.1002/adsc.201200233

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title = "The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold",

abstract = "In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.",

author = "Stephanie Dupuy and Luke Crawford and Michael Buehl and Slawin, \{Alexandra M. Z.\} and Nolan, \{Steven P.\}",

year = "2012",

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AU - Nolan, Steven P.

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N2 - In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.

AB - In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.

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DO - 10.1002/adsc.201200233

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JO - Advanced Synthesis & Catalysis

JF - Advanced Synthesis & Catalysis

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The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

Abstract

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EPSRC - EP/J011053/1- LATE TRANSITION: Late Transition Metal Hydroxide in Homogeneous Catalysis

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The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

Abstract

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EPSRC - EP/J011053/1- LATE TRANSITION: Late Transition Metal Hydroxide in Homogeneous Catalysis

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