The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

Stephanie Dupuy, Luke Crawford, Michael Buehl, Alexandra M. Z. Slawin, Steven P. Nolan

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.

Original languageEnglish
Pages (from-to)2380-2386
Number of pages7
JournalAdvanced Synthesis & Catalysis
Volume354
Issue number13
DOIs
Publication statusPublished - Sept 2012

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