The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

Stephanie Dupuy; Luke Crawford; Michael Buehl; Alexandra M. Z. Slawin; Steven P. Nolan

doi:10.1002/adsc.201200233

The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

Stephanie Dupuy, Luke Crawford, Michael Buehl, Alexandra M. Z. Slawin, Steven P. Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.

Original language	English
Pages (from-to)	2380-2386
Number of pages	7
Journal	Advanced Synthesis & Catalysis
Volume	354
Issue number	13
DOIs	https://doi.org/10.1002/adsc.201200233
Publication status	Published - Sept 2012

Access to Document

10.1002/adsc.201200233

EPSRC - EP/J011053/1- LATE TRANSITION: Late Transition Metal Hydroxide in Homogeneous Catalysis
Nolan, S. P. (PI)
EPSRC
15/03/12 → 14/03/15
Project: Standard

Cite this

@article{c14f56526c2445ca9a1e904934ee7075,

title = "The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold",

abstract = "In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.",

author = "Stephanie Dupuy and Luke Crawford and Michael Buehl and Slawin, {Alexandra M. Z.} and Nolan, {Steven P.}",

year = "2012",

month = sep,

doi = "10.1002/adsc.201200233",

language = "English",

volume = "354",

pages = "2380--2386",

journal = "Advanced Synthesis & Catalysis",

issn = "1615-4150",

publisher = "John Wiley & Sons, Ltd",

number = "13",

}

TY - JOUR

T1 - The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

AU - Dupuy, Stephanie

AU - Crawford, Luke

AU - Buehl, Michael

AU - Slawin, Alexandra M. Z.

AU - Nolan, Steven P.

PY - 2012/9

Y1 - 2012/9

N2 - In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.

AB - In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.

U2 - 10.1002/adsc.201200233

DO - 10.1002/adsc.201200233

M3 - Article

SN - 1615-4150

VL - 354

SP - 2380

EP - 2386

JO - Advanced Synthesis & Catalysis

JF - Advanced Synthesis & Catalysis

IS - 13

ER -

The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

Abstract

Access to Document

Fingerprint

Projects

EPSRC - EP/J011053/1- LATE TRANSITION: Late Transition Metal Hydroxide in Homogeneous Catalysis

Cite this