THE PREPARATION, X-RAY CRYSTAL-STRUCTURE AND THEORETICAL-STUDY OF [COCP2][S3N3], (CP = CYCLOPENTADIENYL), A NOVEL STACKING COMPOUND INCORPORATING MULTIPLE C-H...N(P-PI) INTERACTIONS

P N  JAGG; P F  KELLY; H S  RZEPA; D J  WILLIAMS; J D  WOOLLINS; W  WYLIE

THE PREPARATION, X-RAY CRYSTAL-STRUCTURE AND THEORETICAL-STUDY OF [COCP2][S3N3], (CP = CYCLOPENTADIENYL), A NOVEL STACKING COMPOUND INCORPORATING MULTIPLE C-H...N(P-PI) INTERACTIONS

P N JAGG, P F KELLY, H S RZEPA, D J WILLIAMS, J D WOOLLINS, W WYLIE

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of cobaltocene, [CoCp2], with S4N4 in tetrahydrofuran (thf) results in precipitation of the cobaltocenium salt [CoCp2][S3N3] 1 in good yield; the X-ray crystal structure together with theoretical calculations reveal an accumulation of unique C-H...N...H-C (p-pi) interactions that result in the formation of continuous stacks of alternating cations and anions.

Original language	English
Pages (from-to)	942-944
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	14
Publication status	Published - 15 Jul 1991

Keywords

TETRASULFUR TETRANITRIDE
ANIONS

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@article{dc8e618bd20448589f9221c0f639ab79,

title = "THE PREPARATION, X-RAY CRYSTAL-STRUCTURE AND THEORETICAL-STUDY OF [COCP2][S3N3], (CP = CYCLOPENTADIENYL), A NOVEL STACKING COMPOUND INCORPORATING MULTIPLE C-H...N(P-PI) INTERACTIONS",

abstract = "Reaction of cobaltocene, [CoCp2], with S4N4 in tetrahydrofuran (thf) results in precipitation of the cobaltocenium salt [CoCp2][S3N3] 1 in good yield; the X-ray crystal structure together with theoretical calculations reveal an accumulation of unique C-H...N...H-C (p-pi) interactions that result in the formation of continuous stacks of alternating cations and anions.",

keywords = "TETRASULFUR TETRANITRIDE, ANIONS",

author = "JAGG, {P N} and KELLY, {P F} and RZEPA, {H S} and WILLIAMS, {D J} and WOOLLINS, {J D} and W WYLIE",

year = "1991",

month = jul,

day = "15",

language = "English",

pages = "942--944",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "14",

}

THE PREPARATION, X-RAY CRYSTAL-STRUCTURE AND THEORETICAL-STUDY OF [COCP2][S3N3], (CP = CYCLOPENTADIENYL), A NOVEL STACKING COMPOUND INCORPORATING MULTIPLE C-H...N(P-PI) INTERACTIONS. / JAGG, P N ; KELLY, P F ; RZEPA, H S et al.
In: Journal of the Chemical Society, Chemical Communications, No. 14, 15.07.1991, p. 942-944.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - THE PREPARATION, X-RAY CRYSTAL-STRUCTURE AND THEORETICAL-STUDY OF [COCP2][S3N3], (CP = CYCLOPENTADIENYL), A NOVEL STACKING COMPOUND INCORPORATING MULTIPLE C-H...N(P-PI) INTERACTIONS

AU - JAGG, P N

AU - KELLY, P F

AU - RZEPA, H S

AU - WILLIAMS, D J

AU - WOOLLINS, J D

AU - WYLIE, W

PY - 1991/7/15

Y1 - 1991/7/15

N2 - Reaction of cobaltocene, [CoCp2], with S4N4 in tetrahydrofuran (thf) results in precipitation of the cobaltocenium salt [CoCp2][S3N3] 1 in good yield; the X-ray crystal structure together with theoretical calculations reveal an accumulation of unique C-H...N...H-C (p-pi) interactions that result in the formation of continuous stacks of alternating cations and anions.

AB - Reaction of cobaltocene, [CoCp2], with S4N4 in tetrahydrofuran (thf) results in precipitation of the cobaltocenium salt [CoCp2][S3N3] 1 in good yield; the X-ray crystal structure together with theoretical calculations reveal an accumulation of unique C-H...N...H-C (p-pi) interactions that result in the formation of continuous stacks of alternating cations and anions.

KW - TETRASULFUR TETRANITRIDE

KW - ANIONS

M3 - Article

SN - 0022-4936

SP - 942

EP - 944

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 14

ER -

THE PREPARATION, X-RAY CRYSTAL-STRUCTURE AND THEORETICAL-STUDY OF [COCP2][S3N3], (CP = CYCLOPENTADIENYL), A NOVEL STACKING COMPOUND INCORPORATING MULTIPLE C-H...N(P-PI) INTERACTIONS

Abstract

Keywords

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