The preparation of mixed-ligand dithiolene complexes: X-ray structure of Pt(PMe2Ph)2(mnt) and [Bu4N][Au(mnt)2]

Jonathan C. Fitzmaurice; Alexandra Martha Zoya Slawin; David J. Williams; J Derek Woollins; Alan J. Lindsay

doi:10.1016/S0277-5387(00)86574-2

The preparation of mixed-ligand dithiolene complexes: X-ray structure of Pt(PMe₂Ph)₂(mnt) and [Bu₄N][Au(mnt)₂]

Jonathan C. Fitzmaurice, Alexandra Martha Zoya Slawin, David J. Williams, J Derek Woollins, Alan J. Lindsay

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction Of PtCl2(PR3)2 with sodium dithiolates gives mixed-ligand complexes such as Pt(PR3)2(mnt) (1). Attempts to prepare mixed SN/mnt complexes of gold were unsuccessful, [Bu4N][Au(mnt)2] (2) being obtained. New compounds were characterized by IR and NMR spectroscopy and microanalyses, and in the case of 1 and 2 by X-ray crystallography. Both 1 and 2 are square planar. In 2, one of the crystallographically independent anions lies over a symmetry related neighbour.

Original language	English
Pages (from-to)	1561-1565
Number of pages	5
Journal	Polyhedron
Volume	9
Issue number	13
DOIs	https://doi.org/10.1016/S0277-5387(00)86574-2
Publication status	Published - 1990

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title = "The preparation of mixed-ligand dithiolene complexes: X-ray structure of Pt(PMe2Ph)2(mnt) and [Bu4N][Au(mnt)2]",

abstract = "Reaction Of PtCl2(PR3)2 with sodium dithiolates gives mixed-ligand complexes such as Pt(PR3)2(mnt) (1). Attempts to prepare mixed SN/mnt complexes of gold were unsuccessful, [Bu4N][Au(mnt)2] (2) being obtained. New compounds were characterized by IR and NMR spectroscopy and microanalyses, and in the case of 1 and 2 by X-ray crystallography. Both 1 and 2 are square planar. In 2, one of the crystallographically independent anions lies over a symmetry related neighbour.",

author = "Fitzmaurice, \{Jonathan C.\} and Slawin, \{Alexandra Martha Zoya\} and Williams, \{David J.\} and Woollins, \{J Derek\} and Lindsay, \{Alan J.\}",

year = "1990",

doi = "10.1016/S0277-5387(00)86574-2",

language = "English",

volume = "9",

pages = "1561--1565",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "13",

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T1 - The preparation of mixed-ligand dithiolene complexes

T2 - X-ray structure of Pt(PMe2Ph)2(mnt) and [Bu4N][Au(mnt)2]

AU - Fitzmaurice, Jonathan C.

AU - Slawin, Alexandra Martha Zoya

AU - Williams, David J.

AU - Woollins, J Derek

AU - Lindsay, Alan J.

PY - 1990

Y1 - 1990

N2 - Reaction Of PtCl2(PR3)2 with sodium dithiolates gives mixed-ligand complexes such as Pt(PR3)2(mnt) (1). Attempts to prepare mixed SN/mnt complexes of gold were unsuccessful, [Bu4N][Au(mnt)2] (2) being obtained. New compounds were characterized by IR and NMR spectroscopy and microanalyses, and in the case of 1 and 2 by X-ray crystallography. Both 1 and 2 are square planar. In 2, one of the crystallographically independent anions lies over a symmetry related neighbour.

AB - Reaction Of PtCl2(PR3)2 with sodium dithiolates gives mixed-ligand complexes such as Pt(PR3)2(mnt) (1). Attempts to prepare mixed SN/mnt complexes of gold were unsuccessful, [Bu4N][Au(mnt)2] (2) being obtained. New compounds were characterized by IR and NMR spectroscopy and microanalyses, and in the case of 1 and 2 by X-ray crystallography. Both 1 and 2 are square planar. In 2, one of the crystallographically independent anions lies over a symmetry related neighbour.

UR - https://www.scopus.com/pages/publications/0001427512

U2 - 10.1016/S0277-5387(00)86574-2

DO - 10.1016/S0277-5387(00)86574-2

M3 - Article

SN - 0277-5387

VL - 9

SP - 1561

EP - 1565

JO - Polyhedron

JF - Polyhedron

IS - 13

ER -

The preparation of mixed-ligand dithiolene complexes: X-ray structure of Pt(PMe₂Ph)₂(mnt) and [Bu₄N][Au(mnt)₂]

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