TY - JOUR
T1 - The preparation of mixed-ligand dithiolene complexes
T2 - X-ray structure of Pt(PMe2Ph)2(mnt) and [Bu4N][Au(mnt)2]
AU - Fitzmaurice, Jonathan C.
AU - Slawin, Alexandra Martha Zoya
AU - Williams, David J.
AU - Woollins, J Derek
AU - Lindsay, Alan J.
PY - 1990
Y1 - 1990
N2 - Reaction Of PtCl2(PR3)2 with sodium dithiolates gives mixed-ligand complexes such as Pt(PR3)2(mnt) (1). Attempts to prepare mixed SN/mnt complexes of gold were unsuccessful, [Bu4N][Au(mnt)2] (2) being obtained. New compounds were characterized by IR and NMR spectroscopy and microanalyses, and in the case of 1 and 2 by X-ray crystallography. Both 1 and 2 are square planar. In 2, one of the crystallographically independent anions lies over a symmetry related neighbour.
AB - Reaction Of PtCl2(PR3)2 with sodium dithiolates gives mixed-ligand complexes such as Pt(PR3)2(mnt) (1). Attempts to prepare mixed SN/mnt complexes of gold were unsuccessful, [Bu4N][Au(mnt)2] (2) being obtained. New compounds were characterized by IR and NMR spectroscopy and microanalyses, and in the case of 1 and 2 by X-ray crystallography. Both 1 and 2 are square planar. In 2, one of the crystallographically independent anions lies over a symmetry related neighbour.
U2 - 10.1016/S0277-5387(00)86574-2
DO - 10.1016/S0277-5387(00)86574-2
M3 - Article
SN - 0277-5387
VL - 9
SP - 1561
EP - 1565
JO - Polyhedron
JF - Polyhedron
IS - 13
ER -