Abstract
The preparation of metalla-sulphur-nitrogen and metalla-selenium-nitrogen complexes from reactions in liquid ammonia is described. For example, reaction of PtCl2(PR3)2 with [S4N3]Cl in liquid ammonia yields Pt(S2N2)(PR3)2. Similar reactions with SOCl2, SO2Cl2 and SeCl4 give complexes containing NSO-, [SO2(NH)2]2- and Se2N2(2-) ligands respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 217-222 |
| Number of pages | 6 |
| Journal | Journal de Physique IV - Proceedings |
| Volume | 1 |
| Issue number | C5 |
| DOIs | |
| Publication status | Published - Dec 1991 |
Keywords
- X-RAY STRUCTURE
- SULFUR NITROGEN-COMPOUNDS
- LIGANDS