The preparation of dialkylthiophosphonatoamines. X-ray structures of (EtO)(2)PSNHC6H4NO2 and [(EtO)(2)PSNHC6H4NO2](2)PdCl2

J R  Phillips; D J  Williams; A M Z  Slawin; J D  Woollins

The preparation of dialkylthiophosphonatoamines. X-ray structures of (EtO)(2)PSNHC6H4NO2 and [(EtO)(2)PSNHC6H4NO2](2)PdCl2

J R Phillips, D J Williams, A M Z Slawin, J D Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of RR'NH with (EtO)(2)P(S)Cl gave (EtO)(2)P(S)NRR' (R, R' = Bu, Et, Me, H but not all combinations, R = H, R' = p-O2NC6H4- = the title compound). The crystal structures of the title compounds show that the aryl-N-P-S backbone is approximately co-planar both in the free compound and its palladium complex. In the palladium complex, the ligands are tilted with respect to the coordination plane. Copyright (C) 1996 Elsevier Science Ltd

Original language	English
Pages (from-to)	3725-3729
Number of pages	5
Journal	Polyhedron
Volume	15
Issue number	21
Publication status	Published - 1996

Keywords

METAL-COMPLEXES

Cite this

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abstract = "Reaction of RR'NH with (EtO)(2)P(S)Cl gave (EtO)(2)P(S)NRR' (R, R' = Bu, Et, Me, H but not all combinations, R = H, R' = p-O2NC6H4- = the title compound). The crystal structures of the title compounds show that the aryl-N-P-S backbone is approximately co-planar both in the free compound and its palladium complex. In the palladium complex, the ligands are tilted with respect to the coordination plane. Copyright (C) 1996 Elsevier Science Ltd",

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year = "1996",

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pages = "3725--3729",

journal = "Polyhedron",

issn = "0277-5387",

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T1 - The preparation of dialkylthiophosphonatoamines. X-ray structures of (EtO)(2)PSNHC6H4NO2 and [(EtO)(2)PSNHC6H4NO2](2)PdCl2

AU - Phillips, J R

AU - Williams, D J

AU - Slawin, A M Z

AU - Woollins, J D

PY - 1996

Y1 - 1996

N2 - Reaction of RR'NH with (EtO)(2)P(S)Cl gave (EtO)(2)P(S)NRR' (R, R' = Bu, Et, Me, H but not all combinations, R = H, R' = p-O2NC6H4- = the title compound). The crystal structures of the title compounds show that the aryl-N-P-S backbone is approximately co-planar both in the free compound and its palladium complex. In the palladium complex, the ligands are tilted with respect to the coordination plane. Copyright (C) 1996 Elsevier Science Ltd

AB - Reaction of RR'NH with (EtO)(2)P(S)Cl gave (EtO)(2)P(S)NRR' (R, R' = Bu, Et, Me, H but not all combinations, R = H, R' = p-O2NC6H4- = the title compound). The crystal structures of the title compounds show that the aryl-N-P-S backbone is approximately co-planar both in the free compound and its palladium complex. In the palladium complex, the ligands are tilted with respect to the coordination plane. Copyright (C) 1996 Elsevier Science Ltd

KW - METAL-COMPLEXES

UR - https://www.scopus.com/pages/publications/0038975586

M3 - Article

SN - 0277-5387

VL - 15

SP - 3725

EP - 3729

JO - Polyhedron

JF - Polyhedron

IS - 21

ER -

The preparation of dialkylthiophosphonatoamines. X-ray structures of (EtO)(2)PSNHC6H4NO2 and [(EtO)(2)PSNHC6H4NO2](2)PdCl2

Abstract

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