The preparation of dialkylthiophosphonatoamines. X-ray structures of (EtO)(2)PSNHC6H4NO2 and [(EtO)(2)PSNHC6H4NO2](2)PdCl2

J R Phillips, D J Williams, A M Z Slawin, J D Woollins

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5 Citations (Scopus)

Abstract

Reaction of RR'NH with (EtO)(2)P(S)Cl gave (EtO)(2)P(S)NRR' (R, R' = Bu, Et, Me, H but not all combinations, R = H, R' = p-O2NC6H4- = the title compound). The crystal structures of the title compounds show that the aryl-N-P-S backbone is approximately co-planar both in the free compound and its palladium complex. In the palladium complex, the ligands are tilted with respect to the coordination plane. Copyright (C) 1996 Elsevier Science Ltd

Original languageEnglish
Pages (from-to)3725-3729
Number of pages5
JournalPolyhedron
Volume15
Issue number21
Publication statusPublished - 1996

Keywords

  • METAL-COMPLEXES

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