THE PREPARATION AND X-RAY STRUCTURE OF [NBU4][FAC-PTBR3(S4N4)]

V C  GINN; P F  KELLY; A M Z  SLAWIN; D J  WILLIAMS; J D  WOOLLINS

doi:10.1016/S0277-5387(00)88202-9

THE PREPARATION AND X-RAY STRUCTURE OF [NBU4][FAC-PTBR3(S4N4)]

V C GINN, P F KELLY, A M Z SLAWIN, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of [NBu4][Pt2Br6] with S4N4 gives the title compound, which has been characterized by N-15/Pt-195 NMR and X-ray crystallography. The anion consists of fused PtS2N2 and PtS3N2 rings with coordination to the platinum via two sulphur atoms and one nitrogen. The five-membered ring is essentially planar, whereas the six-membered ring is planar with the exception of the coordinated sulphur atom which is common to both rings. The N-S-N angles can be related to the magnitude of the 2J{N-15-N-15} coupling constants.

Original language	English
Pages (from-to)	1135-1139
Number of pages	5
Journal	Polyhedron
Volume	12
Issue number	10
DOIs	https://doi.org/10.1016/S0277-5387(00)88202-9
Publication status	Published - May 1993

Keywords

SULFUR NITROGEN LIGANDS
COMPLEXES
S4N4

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title = "THE PREPARATION AND X-RAY STRUCTURE OF [NBU4][FAC-PTBR3(S4N4)]",

abstract = "Reaction of [NBu4][Pt2Br6] with S4N4 gives the title compound, which has been characterized by N-15/Pt-195 NMR and X-ray crystallography. The anion consists of fused PtS2N2 and PtS3N2 rings with coordination to the platinum via two sulphur atoms and one nitrogen. The five-membered ring is essentially planar, whereas the six-membered ring is planar with the exception of the coordinated sulphur atom which is common to both rings. The N-S-N angles can be related to the magnitude of the 2J\{N-15-N-15\} coupling constants.",

keywords = "SULFUR NITROGEN LIGANDS, COMPLEXES, S4N4",

author = "GINN, \{V C\} and KELLY, \{P F\} and SLAWIN, \{A M Z\} and WILLIAMS, \{D J\} and WOOLLINS, \{J D\}",

year = "1993",

month = may,

doi = "10.1016/S0277-5387(00)88202-9",

language = "English",

volume = "12",

pages = "1135--1139",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

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T1 - THE PREPARATION AND X-RAY STRUCTURE OF [NBU4][FAC-PTBR3(S4N4)]

AU - GINN, V C

AU - KELLY, P F

AU - SLAWIN, A M Z

AU - WILLIAMS, D J

AU - WOOLLINS, J D

PY - 1993/5

Y1 - 1993/5

N2 - Reaction of [NBu4][Pt2Br6] with S4N4 gives the title compound, which has been characterized by N-15/Pt-195 NMR and X-ray crystallography. The anion consists of fused PtS2N2 and PtS3N2 rings with coordination to the platinum via two sulphur atoms and one nitrogen. The five-membered ring is essentially planar, whereas the six-membered ring is planar with the exception of the coordinated sulphur atom which is common to both rings. The N-S-N angles can be related to the magnitude of the 2J{N-15-N-15} coupling constants.

AB - Reaction of [NBu4][Pt2Br6] with S4N4 gives the title compound, which has been characterized by N-15/Pt-195 NMR and X-ray crystallography. The anion consists of fused PtS2N2 and PtS3N2 rings with coordination to the platinum via two sulphur atoms and one nitrogen. The five-membered ring is essentially planar, whereas the six-membered ring is planar with the exception of the coordinated sulphur atom which is common to both rings. The N-S-N angles can be related to the magnitude of the 2J{N-15-N-15} coupling constants.

KW - SULFUR NITROGEN LIGANDS

KW - COMPLEXES

KW - S4N4

UR - https://www.scopus.com/pages/publications/14044271953

U2 - 10.1016/S0277-5387(00)88202-9

DO - 10.1016/S0277-5387(00)88202-9

M3 - Article

SN - 0277-5387

VL - 12

SP - 1135

EP - 1139

JO - Polyhedron

JF - Polyhedron

IS - 10

ER -

THE PREPARATION AND X-RAY STRUCTURE OF [NBU4][FAC-PTBR3(S4N4)]

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Keywords

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