THE PREPARATION AND X-RAY STRUCTURE OF [NBU4][FAC-PTBR3(S4N4)]

V C GINN, P F KELLY, A M Z SLAWIN, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Reaction of [NBu4][Pt2Br6] with S4N4 gives the title compound, which has been characterized by N-15/Pt-195 NMR and X-ray crystallography. The anion consists of fused PtS2N2 and PtS3N2 rings with coordination to the platinum via two sulphur atoms and one nitrogen. The five-membered ring is essentially planar, whereas the six-membered ring is planar with the exception of the coordinated sulphur atom which is common to both rings. The N-S-N angles can be related to the magnitude of the 2J{N-15-N-15} coupling constants.

Original languageEnglish
Pages (from-to)1135-1139
Number of pages5
JournalPolyhedron
Volume12
Issue number10
DOIs
Publication statusPublished - May 1993

Keywords

  • SULFUR NITROGEN LIGANDS
  • COMPLEXES
  • S4N4

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