The Preparation and X-Ray Structure of [M{SePPh2)2N}2] , M = Ni, Pd, Pt

C Papadimitriou; P Veltsistas; J Novosad; R Cea-Olivares; A Toscano; P García y García; M López-Cardosa; Alexandra Martha Zoya Slawin; John Derek Woollins

The Preparation and X-Ray Structure of [M{SePPh2)2N}2] , M = Ni, Pd, Pt

C Papadimitriou, P Veltsistas, J Novosad, R Cea-Olivares, A Toscano, P García y García, M López-Cardosa, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of [Ni(CH3CO)(2)]4H(2)O, H2PdCl4 or H2PtCl6 with HN[P(Se)Ph-2](2) in water/acetone gave the title compounds in good yield. The compounds were characterised by IR/Raman, NMR and X-ray crystallography. The square planar metal centres form parts of spiro pseudo-boat rings. The X-ray structures allow comparison of the radii of Pt and Pd atoms. (C) 1997 Elsevier Science Ltd.

Original language	English
Pages (from-to)	2727-2729
Number of pages	3
Journal	Polyhedron
Volume	16
Publication status	Published - 1997

Keywords

platinum
palladium
nickel
chelate
X-ray structure

Cite this

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title = "The Preparation and X-Ray Structure of [M{SePPh2)2N}2] , M = Ni, Pd, Pt",

abstract = "Reaction of [Ni(CH3CO)(2)]4H(2)O, H2PdCl4 or H2PtCl6 with HN[P(Se)Ph-2](2) in water/acetone gave the title compounds in good yield. The compounds were characterised by IR/Raman, NMR and X-ray crystallography. The square planar metal centres form parts of spiro pseudo-boat rings. The X-ray structures allow comparison of the radii of Pt and Pd atoms. (C) 1997 Elsevier Science Ltd.",

keywords = "platinum, palladium, nickel, chelate, X-ray structure",

author = "C Papadimitriou and P Veltsistas and J Novosad and R Cea-Olivares and A Toscano and {Garc{\'i}a y Garc{\'i}a}, P and M L{\'o}pez-Cardosa and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

year = "1997",

language = "English",

volume = "16",

pages = "2727--2729",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

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TY - JOUR

T1 - The Preparation and X-Ray Structure of [M{SePPh2)2N}2] , M = Ni, Pd, Pt

AU - Papadimitriou, C

AU - Veltsistas, P

AU - Novosad, J

AU - Cea-Olivares, R

AU - Toscano, A

AU - García y García, P

AU - López-Cardosa, M

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 1997

Y1 - 1997

N2 - Reaction of [Ni(CH3CO)(2)]4H(2)O, H2PdCl4 or H2PtCl6 with HN[P(Se)Ph-2](2) in water/acetone gave the title compounds in good yield. The compounds were characterised by IR/Raman, NMR and X-ray crystallography. The square planar metal centres form parts of spiro pseudo-boat rings. The X-ray structures allow comparison of the radii of Pt and Pd atoms. (C) 1997 Elsevier Science Ltd.

AB - Reaction of [Ni(CH3CO)(2)]4H(2)O, H2PdCl4 or H2PtCl6 with HN[P(Se)Ph-2](2) in water/acetone gave the title compounds in good yield. The compounds were characterised by IR/Raman, NMR and X-ray crystallography. The square planar metal centres form parts of spiro pseudo-boat rings. The X-ray structures allow comparison of the radii of Pt and Pd atoms. (C) 1997 Elsevier Science Ltd.

KW - platinum

KW - palladium

KW - nickel

KW - chelate

KW - X-ray structure

UR - http://www.scopus.com/inward/record.url?scp=0000955594&partnerID=8YFLogxK

M3 - Article

SN - 0277-5387

VL - 16

SP - 2727

EP - 2729

JO - Polyhedron

JF - Polyhedron

ER -

The Preparation and X-Ray Structure of [M{SePPh2)2N}2] , M = Ni, Pd, Pt

Abstract

Keywords

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