The Preparation and X-Ray Structure of [M{SePPh2)2N}2] , M = Ni, Pd, Pt

C Papadimitriou, P Veltsistas, J Novosad, R Cea-Olivares, A Toscano, P García y García, M López-Cardosa, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journalArticlepeer-review

42 Citations (Scopus)

Abstract

Reaction of [Ni(CH3CO)(2)]4H(2)O, H2PdCl4 or H2PtCl6 with HN[P(Se)Ph-2](2) in water/acetone gave the title compounds in good yield. The compounds were characterised by IR/Raman, NMR and X-ray crystallography. The square planar metal centres form parts of spiro pseudo-boat rings. The X-ray structures allow comparison of the radii of Pt and Pd atoms. (C) 1997 Elsevier Science Ltd.

Original languageEnglish
Pages (from-to)2727-2729
Number of pages3
JournalPolyhedron
Volume16
Publication statusPublished - 1997

Keywords

  • platinum
  • palladium
  • nickel
  • chelate
  • X-ray structure

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