THE PREPARATION AND X-RAY STRUCTURE OF A 7-COORDINATE TRIS(CATECHOLAMIDE)NIOBIUM(V) COMPLEX

D F  EVANS; A M Z  SLAWIN; D J  WILLIAMS; C Y  WONG; J D  WOOLLINS

doi:10.1016/S0277-5387(00)87192-2

THE PREPARATION AND X-RAY STRUCTURE OF A 7-COORDINATE TRIS(CATECHOLAMIDE)NIOBIUM(V) COMPLEX

D F EVANS, A M Z SLAWIN, D J WILLIAMS, C Y WONG, J D WOOLLINS

Research output: Contribution to journal › Comment/debate › peer-review

5 Citations (Scopus)

Abstract

The preparation and crystal structure of the Nb(V)(Htrencam) . DMSO complex is reported [where H-6trencam is the hexadentate tris(catecholamide) ligand and DMSO is dimethylsulphoxide], revealing a cavitand-like arrangement of the three catecholamide groups with the protonated non-binding nitrogen atom directed inwards to the niobium atom.

Original language	English
Pages (from-to)	1103-1106
Number of pages	4
Journal	Polyhedron
Volume	12
Issue number	9
DOIs	https://doi.org/10.1016/S0277-5387(00)87192-2
Publication status	Published - May 1993

Keywords

CRYSTAL-STRUCTURE
ELECTROCHEMISTRY

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10.1016/S0277-5387(00)87192-2

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title = "THE PREPARATION AND X-RAY STRUCTURE OF A 7-COORDINATE TRIS(CATECHOLAMIDE)NIOBIUM(V) COMPLEX",

abstract = "The preparation and crystal structure of the Nb(V)(Htrencam) . DMSO complex is reported [where H-6trencam is the hexadentate tris(catecholamide) ligand and DMSO is dimethylsulphoxide], revealing a cavitand-like arrangement of the three catecholamide groups with the protonated non-binding nitrogen atom directed inwards to the niobium atom.",

keywords = "CRYSTAL-STRUCTURE, ELECTROCHEMISTRY",

author = "EVANS, {D F} and SLAWIN, {A M Z} and WILLIAMS, {D J} and WONG, {C Y} and WOOLLINS, {J D}",

year = "1993",

month = may,

doi = "10.1016/S0277-5387(00)87192-2",

language = "English",

volume = "12",

pages = "1103--1106",

journal = "Polyhedron",

issn = "0277-5387",

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T1 - THE PREPARATION AND X-RAY STRUCTURE OF A 7-COORDINATE TRIS(CATECHOLAMIDE)NIOBIUM(V) COMPLEX

AU - EVANS, D F

AU - SLAWIN, A M Z

AU - WILLIAMS, D J

AU - WONG, C Y

AU - WOOLLINS, J D

PY - 1993/5

Y1 - 1993/5

N2 - The preparation and crystal structure of the Nb(V)(Htrencam) . DMSO complex is reported [where H-6trencam is the hexadentate tris(catecholamide) ligand and DMSO is dimethylsulphoxide], revealing a cavitand-like arrangement of the three catecholamide groups with the protonated non-binding nitrogen atom directed inwards to the niobium atom.

AB - The preparation and crystal structure of the Nb(V)(Htrencam) . DMSO complex is reported [where H-6trencam is the hexadentate tris(catecholamide) ligand and DMSO is dimethylsulphoxide], revealing a cavitand-like arrangement of the three catecholamide groups with the protonated non-binding nitrogen atom directed inwards to the niobium atom.

KW - CRYSTAL-STRUCTURE

KW - ELECTROCHEMISTRY

U2 - 10.1016/S0277-5387(00)87192-2

DO - 10.1016/S0277-5387(00)87192-2

M3 - Comment/debate

SN - 0277-5387

VL - 12

SP - 1103

EP - 1106

JO - Polyhedron

JF - Polyhedron

IS - 9

ER -

THE PREPARATION AND X-RAY STRUCTURE OF A 7-COORDINATE TRIS(CATECHOLAMIDE)NIOBIUM(V) COMPLEX

Abstract

Keywords

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