TY - GEN
T1 - The preparation and X-ray crystal structure of [Co(Ph2SNH)6]Cl2 a homoleptic sulfimide complex exhibiting cooperative, directed hydrogen bonds between cations and anions
AU - Kelly, PF
AU - Slawin, Alexandra Martha Zoya
AU - Waring, KW
N1 - Inorg.Chem.Comm
PY - 1998/7
Y1 - 1998/7
N2 - At ambient temperatures, in CH3CN, a six-fold excess of S,S-diphenylsulfimide (1) reacts with anhydrous CoCl2 to give [Co(Ph2SNH)(6)] Cl-2 (2), the first example of a homoleptic sulfimide complex. In addition to the expected octahedral coordination geometry, X-ray crystallography reveals significant directed hydrogen bonding from the N-H groups on the ligands to the chlorides. Thus the three N-H bonds on opposite coordination faces act as cooperative hydrogen-bonding pockets for the chloride counterions. (C) 1998 Elsevier Science S.A. All rights reserved.
AB - At ambient temperatures, in CH3CN, a six-fold excess of S,S-diphenylsulfimide (1) reacts with anhydrous CoCl2 to give [Co(Ph2SNH)(6)] Cl-2 (2), the first example of a homoleptic sulfimide complex. In addition to the expected octahedral coordination geometry, X-ray crystallography reveals significant directed hydrogen bonding from the N-H groups on the ligands to the chlorides. Thus the three N-H bonds on opposite coordination faces act as cooperative hydrogen-bonding pockets for the chloride counterions. (C) 1998 Elsevier Science S.A. All rights reserved.
KW - homoleptic sulfimide complexes
KW - crystal structures
KW - octahedral coordination geometry
KW - copper(II) complexes
UR - http://www.scopus.com/inward/record.url?scp=0000998829&partnerID=8YFLogxK
M3 - Other contribution
VL - 1
ER -