The preparation and structures of Ph2P(E)OH and Ph2P(E)OP(E)Ph-2 (E=S, Se)

M J Pilkington, A M Z Slawin, D J Williams, J D Woollins

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Abstract

The preparation and characterization of the title compounds is reported. The selenium compounds have been characterized by x-ray crystallography. Ph2P(Se)OH 1 Pbca a = 6.203(1), b = 16.949(4), c = 22.939(5) Angstrom, Z = 8, 1523 observed data, R = 0.033, R-w = 0.038. Ph2P(Se)OP(Se)Ph(2)2 C2/c a = 15.426(4), b = 9.232(3), c = 18.027(5) Angstrom, beta = 118.40(2)degrees, Z = 4, 1446 observed data, R = 0.028, R-w = 0.030.

Original languageEnglish
Pages (from-to)145-151
Number of pages7
JournalMain Group Chemistry
Volume1
Issue number1
DOIs
Publication statusPublished - 1995

Keywords

  • PLATINUM

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