The Preparation and Coordination Chemistry of Phosphorus(III) Derivatives of Dialkyl Hydrazines.

Alexandra Martha Zoya Slawin; M Wainwright; John Derek Woollins

doi:10.1039/b107072j

The Preparation and Coordination Chemistry of Phosphorus(III) Derivatives of Dialkyl Hydrazines.

Alexandra Martha Zoya Slawin, M Wainwright, John Derek Woollins

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Abstract

The formation of the new inorganic hydrazine based ligands R2PNR'NR'PR2 [R' = Et, R = Cl, Ph, OPh, CH2Ph, o-MeOC6H4: R' = Me, R = o-MeC6H4, o-MeOC6H4] is reported. These ligands have been complexed at Pd(II) and Pt(II) centres and demonstrative X-ray structures have been determined. When R = o-MeOC6H4 the oxygen atoms of two of the OMe groups coordinate pseudo axially.

Original language	English
Pages (from-to)	513-519
Number of pages	7
Journal	Journal of the Chemical Society, Dalton Transactions
DOIs	https://doi.org/10.1039/b107072j
Publication status	Published - 2002

Keywords

TRANSITION-METAL CHEMISTRY
MAIN-GROUP HYDRAZIDES
COMPLEXES
BIS(DIPHENYLPHOSPHINO)AMINE
UREA
BOND

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title = "The Preparation and Coordination Chemistry of Phosphorus(III) Derivatives of Dialkyl Hydrazines.",

abstract = "The formation of the new inorganic hydrazine based ligands R2PNR'NR'PR2 [R' = Et, R = Cl, Ph, OPh, CH2Ph, o-MeOC6H4: R' = Me, R = o-MeC6H4, o-MeOC6H4] is reported. These ligands have been complexed at Pd(II) and Pt(II) centres and demonstrative X-ray structures have been determined. When R = o-MeOC6H4 the oxygen atoms of two of the OMe groups coordinate pseudo axially.",

keywords = "TRANSITION-METAL CHEMISTRY, MAIN-GROUP HYDRAZIDES, COMPLEXES, BIS(DIPHENYLPHOSPHINO)AMINE, UREA, BOND",

author = "Slawin, \{Alexandra Martha Zoya\} and M Wainwright and Woollins, \{John Derek\}",

year = "2002",

doi = "10.1039/b107072j",

language = "English",

pages = "513--519",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - The Preparation and Coordination Chemistry of Phosphorus(III) Derivatives of Dialkyl Hydrazines.

AU - Slawin, Alexandra Martha Zoya

AU - Wainwright, M

AU - Woollins, John Derek

PY - 2002

Y1 - 2002

N2 - The formation of the new inorganic hydrazine based ligands R2PNR'NR'PR2 [R' = Et, R = Cl, Ph, OPh, CH2Ph, o-MeOC6H4: R' = Me, R = o-MeC6H4, o-MeOC6H4] is reported. These ligands have been complexed at Pd(II) and Pt(II) centres and demonstrative X-ray structures have been determined. When R = o-MeOC6H4 the oxygen atoms of two of the OMe groups coordinate pseudo axially.

AB - The formation of the new inorganic hydrazine based ligands R2PNR'NR'PR2 [R' = Et, R = Cl, Ph, OPh, CH2Ph, o-MeOC6H4: R' = Me, R = o-MeC6H4, o-MeOC6H4] is reported. These ligands have been complexed at Pd(II) and Pt(II) centres and demonstrative X-ray structures have been determined. When R = o-MeOC6H4 the oxygen atoms of two of the OMe groups coordinate pseudo axially.

KW - TRANSITION-METAL CHEMISTRY

KW - MAIN-GROUP HYDRAZIDES

KW - COMPLEXES

KW - BIS(DIPHENYLPHOSPHINO)AMINE

KW - UREA

KW - BOND

UR - https://www.scopus.com/pages/publications/0036008066

U2 - 10.1039/b107072j

DO - 10.1039/b107072j

M3 - Article

SN - 1472-7773

SP - 513

EP - 519

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

ER -

The Preparation and Coordination Chemistry of Phosphorus(III) Derivatives of Dialkyl Hydrazines.

Abstract

Keywords

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