The Preparation and Coordination Chemistry of Phosphorus(III) Derivatives of Dialkyl Hydrazines.

Alexandra Martha Zoya Slawin, M Wainwright, John Derek Woollins

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)

Abstract

The formation of the new inorganic hydrazine based ligands R2PNR'NR'PR2 [R' = Et, R = Cl, Ph, OPh, CH2Ph, o-MeOC6H4: R' = Me, R = o-MeC6H4, o-MeOC6H4] is reported. These ligands have been complexed at Pd(II) and Pt(II) centres and demonstrative X-ray structures have been determined. When R = o-MeOC6H4 the oxygen atoms of two of the OMe groups coordinate pseudo axially.

Original languageEnglish
Pages (from-to)513-519
Number of pages7
JournalJournal of the Chemical Society, Dalton Transactions
DOIs
Publication statusPublished - 2002

Keywords

  • TRANSITION-METAL CHEMISTRY
  • MAIN-GROUP HYDRAZIDES
  • COMPLEXES
  • BIS(DIPHENYLPHOSPHINO)AMINE
  • UREA
  • BOND

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