TY - JOUR
T1 - The preparation and complexation of 5,10-bis(diphenylphosphino)phenazine
AU - i Zubiri, Mireia R
AU - Milton, Heather L
AU - Cole-Hamilton, David John
AU - Slawin, Alexandra Martha Zoya
AU - Woollins, John Derek
PY - 2004/2
Y1 - 2004/2
N2 - Reaction of 5,10-dihydrophenazine with two equivalents of Ph2PCl, in the presence of n-BuLi at -78 degreesC in thf gives Ph2PN(C6H4)(C6H4)NPPh2 (1) (1) which can be oxidised with selenium to Ph2P(Se)N(C6H4)(C-6 H-4)NP(Se)Ph-2 (2) (2) or coordinated with Pt(Il) in cis-[PtCl2 {Ph2PN(C6H4)(C6H4)NPPh2}] (3) (3) The structure of 3 reveals a severely distorted (non-planar) phenazine backbone. (C) 2003 Published by Elsevier B.V.
AB - Reaction of 5,10-dihydrophenazine with two equivalents of Ph2PCl, in the presence of n-BuLi at -78 degreesC in thf gives Ph2PN(C6H4)(C6H4)NPPh2 (1) (1) which can be oxidised with selenium to Ph2P(Se)N(C6H4)(C-6 H-4)NP(Se)Ph-2 (2) (2) or coordinated with Pt(Il) in cis-[PtCl2 {Ph2PN(C6H4)(C6H4)NPPh2}] (3) (3) The structure of 3 reveals a severely distorted (non-planar) phenazine backbone. (C) 2003 Published by Elsevier B.V.
KW - X-ray crystallography
KW - synthesis
KW - structure
KW - N BOND FORMATION
KW - PHOSPHINE-LIGANDS
KW - CHEMISTRY
KW - CATALYSIS
KW - ROUTE
UR - https://www.scopus.com/pages/publications/0842299376
UR - http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6VM7-4B4VRXC-3&_user=1026342&_coverDate=02%2F29%2F2004&_alid=178396022&_rdoc=7&_fmt=full&_orig=search&_cdi=6143&_sort=d&_st=4&_docanchor=&_acct=C000050565&_version=1&_urlVersion=0&_userid=1026342&md5=7ac79377f0c322766a794208e3e5572b
U2 - 10.1016/j.inoche.2003.10.019
DO - 10.1016/j.inoche.2003.10.019
M3 - Article
SN - 1387-7003
VL - 7
SP - 201
EP - 203
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 2
ER -