The preparation and characterisation of platinum and palladium phosphine thiocarbonate complexes M(PR3)2(CS3) and Pt(PR3)2(CSeS2)

SA Aucott, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

Reaction of CS2 with NH3(liq) gives the (CS3)(2-) dianion which undergoes in situ reaction with MCl2(PR3)(2) to give M(PR3)(2)(CS3). X-ray analysis of four examples (M = Pt, PR3 = PMe3, PMe2Ph, PPh3, dppp) reveals square planar coordination with the [CS3](2-) dianion being effectively in the same plane as the coordination sphere. The first example of a [CSeS2](2-) complex is also reported. (C) 2000 Elsevier Science Ltd All rights reserved.

Original languageEnglish
Pages (from-to)499-502
Number of pages4
JournalPolyhedron
Volume19
Publication statusPublished - 28 Feb 2000

Keywords

  • platinum
  • palladium
  • phosphine thiocarbonates
  • CRYSTAL-STRUCTURES
  • SPECTRA

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