The preparation and characterisation of platinum and palladium phosphine thiocarbonate complexes M(PR3)2(CS3) and Pt(PR3)2(CSeS2)

SA Aucott; Alexandra Martha Zoya Slawin; John Derek Woollins

The preparation and characterisation of platinum and palladium phosphine thiocarbonate complexes M(PR₃)₂(CS₃) and Pt(PR₃)₂(CSeS₂)

SA Aucott, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of CS2 with NH3(liq) gives the (CS3)(2-) dianion which undergoes in situ reaction with MCl2(PR3)(2) to give M(PR3)(2)(CS3). X-ray analysis of four examples (M = Pt, PR3 = PMe3, PMe2Ph, PPh3, dppp) reveals square planar coordination with the [CS3](2-) dianion being effectively in the same plane as the coordination sphere. The first example of a [CSeS2](2-) complex is also reported. (C) 2000 Elsevier Science Ltd All rights reserved.

Original language	English
Pages (from-to)	499-502
Number of pages	4
Journal	Polyhedron
Volume	19
Publication status	Published - 28 Feb 2000

Keywords

platinum
palladium
phosphine thiocarbonates
CRYSTAL-STRUCTURES
SPECTRA

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abstract = "Reaction of CS2 with NH3(liq) gives the (CS3)(2-) dianion which undergoes in situ reaction with MCl2(PR3)(2) to give M(PR3)(2)(CS3). X-ray analysis of four examples (M = Pt, PR3 = PMe3, PMe2Ph, PPh3, dppp) reveals square planar coordination with the [CS3](2-) dianion being effectively in the same plane as the coordination sphere. The first example of a [CSeS2](2-) complex is also reported. (C) 2000 Elsevier Science Ltd All rights reserved.",

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T1 - The preparation and characterisation of platinum and palladium phosphine thiocarbonate complexes M(PR3)2(CS3) and Pt(PR3)2(CSeS2)

AU - Aucott, SA

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 2000/2/28

Y1 - 2000/2/28

N2 - Reaction of CS2 with NH3(liq) gives the (CS3)(2-) dianion which undergoes in situ reaction with MCl2(PR3)(2) to give M(PR3)(2)(CS3). X-ray analysis of four examples (M = Pt, PR3 = PMe3, PMe2Ph, PPh3, dppp) reveals square planar coordination with the [CS3](2-) dianion being effectively in the same plane as the coordination sphere. The first example of a [CSeS2](2-) complex is also reported. (C) 2000 Elsevier Science Ltd All rights reserved.

AB - Reaction of CS2 with NH3(liq) gives the (CS3)(2-) dianion which undergoes in situ reaction with MCl2(PR3)(2) to give M(PR3)(2)(CS3). X-ray analysis of four examples (M = Pt, PR3 = PMe3, PMe2Ph, PPh3, dppp) reveals square planar coordination with the [CS3](2-) dianion being effectively in the same plane as the coordination sphere. The first example of a [CSeS2](2-) complex is also reported. (C) 2000 Elsevier Science Ltd All rights reserved.

KW - platinum

KW - palladium

KW - phosphine thiocarbonates

KW - CRYSTAL-STRUCTURES

KW - SPECTRA

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M3 - Article

SN - 0277-5387

VL - 19

SP - 499

EP - 502

JO - Polyhedron

JF - Polyhedron

ER -

The preparation and characterisation of platinum and palladium phosphine thiocarbonate complexes M(PR₃)₂(CS₃) and Pt(PR₃)₂(CSeS₂)

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