The preferred conformation of α-fluoroamides

JW Banks; AS Batsanov; JA Howard; David O'Hagan; HS Rzepa; S Martin-Santamaria

doi:10.1039/a907452j

The preferred conformation of α-fluoroamides

JW Banks, AS Batsanov, JA Howard, David O'Hagan, HS Rzepa, S Martin-Santamaria

Research output: Contribution to journal › Article › peer-review

Abstract

X-Ray structures of two alpha-fluoroamide derivatives show the O=C-C-F moiety tending towards a trans planar conformation, for which ab initio calculations suggest a deep (up to 8 kcal mol(-1)) potential minimum.

Original language	English
Pages (from-to)	2409-2411
Number of pages	3
Journal	Journal of Chemical Society, Perkin Transactions 2
Issue number	11
DOIs	https://doi.org/10.1039/a907452j
Publication status	Published - Nov 1999

Keywords

FLUOROCARBOXYLIC ACIDS
NEUTRON-DIFFRACTION
FLUORINE
FLUOROGLYCINES
ACCEPTOR

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title = "The preferred conformation of α-fluoroamides",

abstract = "X-Ray structures of two alpha-fluoroamide derivatives show the O=C-C-F moiety tending towards a trans planar conformation, for which ab initio calculations suggest a deep (up to 8 kcal mol(-1)) potential minimum.",

keywords = "FLUOROCARBOXYLIC ACIDS, NEUTRON-DIFFRACTION, FLUORINE, FLUOROGLYCINES, ACCEPTOR",

author = "JW Banks and AS Batsanov and JA Howard and David O'Hagan and HS Rzepa and S Martin-Santamaria",

year = "1999",

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doi = "10.1039/a907452j",

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AU - Banks, JW

AU - Batsanov, AS

AU - Howard, JA

AU - O'Hagan, David

AU - Rzepa, HS

AU - Martin-Santamaria, S

PY - 1999/11

Y1 - 1999/11

N2 - X-Ray structures of two alpha-fluoroamide derivatives show the O=C-C-F moiety tending towards a trans planar conformation, for which ab initio calculations suggest a deep (up to 8 kcal mol(-1)) potential minimum.

AB - X-Ray structures of two alpha-fluoroamide derivatives show the O=C-C-F moiety tending towards a trans planar conformation, for which ab initio calculations suggest a deep (up to 8 kcal mol(-1)) potential minimum.

KW - FLUOROCARBOXYLIC ACIDS

KW - NEUTRON-DIFFRACTION

KW - FLUORINE

KW - FLUOROGLYCINES

KW - ACCEPTOR

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DO - 10.1039/a907452j

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SP - 2409

EP - 2411

JO - Journal of Chemical Society, Perkin Transactions 2

JF - Journal of Chemical Society, Perkin Transactions 2

IS - 11

ER -

The preferred conformation of α-fluoroamides

Abstract

Keywords

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