The origin of chemoselectivity in the hydrocarbonylation of alkenes catalysed by trialkylphosphine complexes of rhodium

P Cheliatsidou; DF White; David John Cole-Hamilton

doi:10.1039/b412919a

The origin of chemoselectivity in the hydrocarbonylation of alkenes catalysed by trialkylphosphine complexes of rhodium

P Cheliatsidou, DF White, David John Cole-Hamilton

Research output: Contribution to journal › Article › peer-review

Abstract

The formation of monophosphine acyl intermediates explains why PPr3i and PBu3i generate aldehydes in alkene hydrocarbonylation reactions carried out in protic solvents, whilst PEt3, for which the acyl complex contains two phosphines, produces alcohols.

Original language	English
Pages (from-to)	3425-3427
Number of pages	3
Journal	Dalton Transactions
Issue number	21
DOIs	https://doi.org/10.1039/b412919a
Publication status	Published - 2004

Keywords

HYDROFORMYLATION
PHOSPHINES

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10.1039/b412919a

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title = "The origin of chemoselectivity in the hydrocarbonylation of alkenes catalysed by trialkylphosphine complexes of rhodium",

abstract = "The formation of monophosphine acyl intermediates explains why PPr3i and PBu3i generate aldehydes in alkene hydrocarbonylation reactions carried out in protic solvents, whilst PEt3, for which the acyl complex contains two phosphines, produces alcohols.",

keywords = "HYDROFORMYLATION, PHOSPHINES",

author = "P Cheliatsidou and DF White and Cole-Hamilton, {David John}",

year = "2004",

doi = "10.1039/b412919a",

language = "English",

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journal = "Dalton Transactions",

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T1 - The origin of chemoselectivity in the hydrocarbonylation of alkenes catalysed by trialkylphosphine complexes of rhodium

AU - Cheliatsidou, P

AU - White, DF

AU - Cole-Hamilton, David John

PY - 2004

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N2 - The formation of monophosphine acyl intermediates explains why PPr3i and PBu3i generate aldehydes in alkene hydrocarbonylation reactions carried out in protic solvents, whilst PEt3, for which the acyl complex contains two phosphines, produces alcohols.

AB - The formation of monophosphine acyl intermediates explains why PPr3i and PBu3i generate aldehydes in alkene hydrocarbonylation reactions carried out in protic solvents, whilst PEt3, for which the acyl complex contains two phosphines, produces alcohols.

KW - HYDROFORMYLATION

KW - PHOSPHINES

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U2 - 10.1039/b412919a

DO - 10.1039/b412919a

M3 - Article

SN - 1477-9226

SP - 3425

EP - 3427

JO - Dalton Transactions

JF - Dalton Transactions

IS - 21

ER -

The origin of chemoselectivity in the hydrocarbonylation of alkenes catalysed by trialkylphosphine complexes of rhodium

Abstract

Keywords

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