The location of sorbed Kr in silicalite using resonant X-ray diffraction

R. H. Jones; P. Lightfoot; R. M. Ormerod

doi:10.1016/0022-3697(95)00073-9

The location of sorbed Kr in silicalite using resonant X-ray diffraction

R. H. Jones^*, P. Lightfoot, R. M. Ormerod

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The location of sorbed Kr atoms in the zeolite silicalite has been determined by the joint Rietveld refinement of off-edge and on-edge (Kr K-edge) data. Three sites have been determined for the Kr atoms, these being in the sinusoidal channel, the straight channel and at the intersection of these two channels. These sites are in good agreement with previous theoretical studies. There is no reduction in crystal symmetry upon sorption of the Kr; space group Pnma, a = 20.034(1) A ̊, b = 19.835(1) A ̊, c = 13.3569(9) A ̊.

Original language	English
Pages (from-to)	1377-1381
Number of pages	5
Journal	Journal of Physics and Chemistry of Solids
Volume	56
Issue number	10
DOIs	https://doi.org/10.1016/0022-3697(95)00073-9
Publication status	Published - 1 Jan 1995

Keywords

A. microporous materials
C. X-ray diffraction
D. crystal structure

Access to Document

10.1016/0022-3697(95)00073-9

Cite this

@article{bf58bf610270498bae5c4f86c30a88f3,

title = "The location of sorbed Kr in silicalite using resonant X-ray diffraction",

abstract = "The location of sorbed Kr atoms in the zeolite silicalite has been determined by the joint Rietveld refinement of off-edge and on-edge (Kr K-edge) data. Three sites have been determined for the Kr atoms, these being in the sinusoidal channel, the straight channel and at the intersection of these two channels. These sites are in good agreement with previous theoretical studies. There is no reduction in crystal symmetry upon sorption of the Kr; space group Pnma, a = 20.034(1) A ̊, b = 19.835(1) A ̊, c = 13.3569(9) A ̊.",

keywords = "A. microporous materials, C. X-ray diffraction, D. crystal structure",

author = "Jones, \{R. H.\} and P. Lightfoot and Ormerod, \{R. M.\}",

year = "1995",

month = jan,

day = "1",

doi = "10.1016/0022-3697(95)00073-9",

language = "English",

volume = "56",

pages = "1377--1381",

journal = "Journal of Physics and Chemistry of Solids",

issn = "0022-3697",

publisher = "Elsevier",

number = "10",

}

TY - JOUR

T1 - The location of sorbed Kr in silicalite using resonant X-ray diffraction

AU - Jones, R. H.

AU - Lightfoot, P.

AU - Ormerod, R. M.

PY - 1995/1/1

Y1 - 1995/1/1

N2 - The location of sorbed Kr atoms in the zeolite silicalite has been determined by the joint Rietveld refinement of off-edge and on-edge (Kr K-edge) data. Three sites have been determined for the Kr atoms, these being in the sinusoidal channel, the straight channel and at the intersection of these two channels. These sites are in good agreement with previous theoretical studies. There is no reduction in crystal symmetry upon sorption of the Kr; space group Pnma, a = 20.034(1) A ̊, b = 19.835(1) A ̊, c = 13.3569(9) A ̊.

AB - The location of sorbed Kr atoms in the zeolite silicalite has been determined by the joint Rietveld refinement of off-edge and on-edge (Kr K-edge) data. Three sites have been determined for the Kr atoms, these being in the sinusoidal channel, the straight channel and at the intersection of these two channels. These sites are in good agreement with previous theoretical studies. There is no reduction in crystal symmetry upon sorption of the Kr; space group Pnma, a = 20.034(1) A ̊, b = 19.835(1) A ̊, c = 13.3569(9) A ̊.

KW - A. microporous materials

KW - C. X-ray diffraction

KW - D. crystal structure

UR - https://www.scopus.com/pages/publications/0000632310

U2 - 10.1016/0022-3697(95)00073-9

DO - 10.1016/0022-3697(95)00073-9

M3 - Article

AN - SCOPUS:0000632310

SN - 0022-3697

VL - 56

SP - 1377

EP - 1381

JO - Journal of Physics and Chemistry of Solids

JF - Journal of Physics and Chemistry of Solids

IS - 10

ER -

The location of sorbed Kr in silicalite using resonant X-ray diffraction

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this