The ionothermal synthesis of metal organic frameworks, Ln(C9O6H3) ((CH3NH)2CO)2 , using deep eutectic solvents

Farida Himeur Himeur; Irene Stein; David S. Wragg; Alexandra Martha Zoya Slawin; Philip Lightfoot; Russell Edward Morris

doi:10.1016/j.solidstatesciences.2009.05.023

The ionothermal synthesis of metal organic frameworks, Ln(C₉O₆H₃) ((CH₃NH)₂CO)₂ , using deep eutectic solvents

Farida Himeur Himeur, Irene Stein, David S. Wragg, Alexandra Martha Zoya Slawin, Philip Lightfoot, Russell Edward Morris

Research output: Contribution to journal › Article › peer-review

Abstract

Three new isostructural materials Ln(TMA)(DMU)(2)(Ln(C9O6H3)((CH3NH)(2)CO)(2): Ln: La 1, Nd 2, Eu 3; TMA: trimesate, DMU: dimethylurea) have been synthesised ionothermally using a choline chloride/dimethylurea deep eutectic mixture as the solvent. Normally in ionothermal synthesis the urea portion of the deep eutectic solvent is unstable, breaking down to release ammonium cations that act as templates. In the case of 1-3, however, the dimethylurea remains intact and is incorporated into the final structure. (C) 2009 Elsevier Masson SAS. All rights reserved.

Original language	English
Pages (from-to)	418-421
Number of pages	4
Journal	Solid State Sciences
Volume	12
Issue number	4
Early online date	29 May 2009
DOIs	https://doi.org/10.1016/j.solidstatesciences.2009.05.023
Publication status	Published - Apr 2010

Keywords

Metal organic frameworks
Ionothermal synthesis
Deep eutectic solvents
IONIC LIQUIDS
COORDINATION POLYMERS
CHOLINE CHLORIDE/UREA
SINGLE-CRYSTAL
FLUORIDE IONS
ALUMINOPHOSPHATE
DEHYDRATION
COMPLEXES
ANION
LN

Access to Document

10.1016/j.solidstatesciences.2009.05.023

Extending Ionothermal Synthesis: Extending Ionothermal Synthesis
Morris, R. E. (PI) & Lightfoot, P. (CoI)
EPSRC
1/01/08 → 30/06/11
Project: Standard

Cite this

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title = "The ionothermal synthesis of metal organic frameworks, Ln(C9O6H3) ((CH3NH)2CO)2 , using deep eutectic solvents",

abstract = "Three new isostructural materials Ln(TMA)(DMU)(2)(Ln(C9O6H3)((CH3NH)(2)CO)(2): Ln: La 1, Nd 2, Eu 3; TMA: trimesate, DMU: dimethylurea) have been synthesised ionothermally using a choline chloride/dimethylurea deep eutectic mixture as the solvent. Normally in ionothermal synthesis the urea portion of the deep eutectic solvent is unstable, breaking down to release ammonium cations that act as templates. In the case of 1-3, however, the dimethylurea remains intact and is incorporated into the final structure. (C) 2009 Elsevier Masson SAS. All rights reserved.",

keywords = "Metal organic frameworks, Ionothermal synthesis, Deep eutectic solvents, IONIC LIQUIDS, COORDINATION POLYMERS, CHOLINE CHLORIDE/UREA, SINGLE-CRYSTAL, FLUORIDE IONS, ALUMINOPHOSPHATE, DEHYDRATION, COMPLEXES, ANION, LN",

author = "Himeur, {Farida Himeur} and Irene Stein and Wragg, {David S.} and Slawin, {Alexandra Martha Zoya} and Philip Lightfoot and Morris, {Russell Edward}",

year = "2010",

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doi = "10.1016/j.solidstatesciences.2009.05.023",

language = "English",

volume = "12",

pages = "418--421",

journal = "Solid State Sciences",

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T1 - The ionothermal synthesis of metal organic frameworks, Ln(C9O6H3) ((CH3NH)2CO)2 , using deep eutectic solvents

AU - Himeur, Farida Himeur

AU - Stein, Irene

AU - Wragg, David S.

AU - Slawin, Alexandra Martha Zoya

AU - Lightfoot, Philip

AU - Morris, Russell Edward

PY - 2010/4

Y1 - 2010/4

N2 - Three new isostructural materials Ln(TMA)(DMU)(2)(Ln(C9O6H3)((CH3NH)(2)CO)(2): Ln: La 1, Nd 2, Eu 3; TMA: trimesate, DMU: dimethylurea) have been synthesised ionothermally using a choline chloride/dimethylurea deep eutectic mixture as the solvent. Normally in ionothermal synthesis the urea portion of the deep eutectic solvent is unstable, breaking down to release ammonium cations that act as templates. In the case of 1-3, however, the dimethylurea remains intact and is incorporated into the final structure. (C) 2009 Elsevier Masson SAS. All rights reserved.

AB - Three new isostructural materials Ln(TMA)(DMU)(2)(Ln(C9O6H3)((CH3NH)(2)CO)(2): Ln: La 1, Nd 2, Eu 3; TMA: trimesate, DMU: dimethylurea) have been synthesised ionothermally using a choline chloride/dimethylurea deep eutectic mixture as the solvent. Normally in ionothermal synthesis the urea portion of the deep eutectic solvent is unstable, breaking down to release ammonium cations that act as templates. In the case of 1-3, however, the dimethylurea remains intact and is incorporated into the final structure. (C) 2009 Elsevier Masson SAS. All rights reserved.

KW - Metal organic frameworks

KW - Ionothermal synthesis

KW - Deep eutectic solvents

KW - IONIC LIQUIDS

KW - COORDINATION POLYMERS

KW - CHOLINE CHLORIDE/UREA

KW - SINGLE-CRYSTAL

KW - FLUORIDE IONS

KW - ALUMINOPHOSPHATE

KW - DEHYDRATION

KW - COMPLEXES

KW - ANION

KW - LN

U2 - 10.1016/j.solidstatesciences.2009.05.023

DO - 10.1016/j.solidstatesciences.2009.05.023

M3 - Article

SN - 1293-2558

VL - 12

SP - 418

EP - 421

JO - Solid State Sciences

JF - Solid State Sciences

IS - 4

ER -

The ionothermal synthesis of metal organic frameworks, Ln(C9O6H3) ((CH3NH)2CO)2 , using deep eutectic solvents

Abstract

Keywords

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Projects

Extending Ionothermal Synthesis: Extending Ionothermal Synthesis

Cite this

The ionothermal synthesis of metal organic frameworks, Ln(C₉O₆H₃) ((CH₃NH)₂CO)₂ , using deep eutectic solvents