The ionothermal synthesis of metal organic frameworks, Ln(C9O6H3) ((CH3NH)2CO)2 , using deep eutectic solvents

Farida Himeur Himeur, Irene Stein, David S. Wragg, Alexandra Martha Zoya Slawin, Philip Lightfoot, Russell Edward Morris

Research output: Contribution to journalArticlepeer-review

54 Citations (Scopus)

Abstract

Three new isostructural materials Ln(TMA)(DMU)(2)(Ln(C9O6H3)((CH3NH)(2)CO)(2): Ln: La 1, Nd 2, Eu 3; TMA: trimesate, DMU: dimethylurea) have been synthesised ionothermally using a choline chloride/dimethylurea deep eutectic mixture as the solvent. Normally in ionothermal synthesis the urea portion of the deep eutectic solvent is unstable, breaking down to release ammonium cations that act as templates. In the case of 1-3, however, the dimethylurea remains intact and is incorporated into the final structure. (C) 2009 Elsevier Masson SAS. All rights reserved.

Original languageEnglish
Pages (from-to)418-421
Number of pages4
JournalSolid State Sciences
Volume12
Issue number4
Early online date29 May 2009
DOIs
Publication statusPublished - Apr 2010

Keywords

  • Metal organic frameworks
  • Ionothermal synthesis
  • Deep eutectic solvents
  • IONIC LIQUIDS
  • COORDINATION POLYMERS
  • CHOLINE CHLORIDE/UREA
  • SINGLE-CRYSTAL
  • FLUORIDE IONS
  • ALUMINOPHOSPHATE
  • DEHYDRATION
  • COMPLEXES
  • ANION
  • LN

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