The intramolecular beta-fluorine...ammonium interaction in 4- and 8-membered rings

Natalie E. J. Gooseman; David O'Hagan; Alexandra M. Z. Slawin; Andrew M. Teale; David J. Tozer; Robert J. Young

doi:10.1039/b606334a

The intramolecular beta-fluorine...ammonium interaction in 4- and 8-membered rings

Natalie E. J. Gooseman, David O'Hagan, Alexandra M. Z. Slawin, Andrew M. Teale, David J. Tozer, Robert J. Young

Research output: Contribution to journal › Article › peer-review

Abstract

The structures of 3-fluoroazetidinium hydrochloride and 3-fluoro-1,5-diazacyclooctane hydrobromide are explored both by X-ray diffraction analysis and DFT calculations, and the conformations of these molecules are shown to be significantly influenced by the through space C-F center dot center dot center dot N+ interaction.

Original language	English
Pages (from-to)	3190-3192
Number of pages	3
Journal	Chemical Communications
Issue number	30
DOIs	https://doi.org/10.1039/b606334a
Publication status	Published - 2006

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FLUORINE

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title = "The intramolecular beta-fluorine...ammonium interaction in 4- and 8-membered rings",

abstract = "The structures of 3-fluoroazetidinium hydrochloride and 3-fluoro-1,5-diazacyclooctane hydrobromide are explored both by X-ray diffraction analysis and DFT calculations, and the conformations of these molecules are shown to be significantly influenced by the through space C-F center dot center dot center dot N+ interaction.",

keywords = "FLUORINE",

author = "Gooseman, \{Natalie E. J.\} and David O'Hagan and Slawin, \{Alexandra M. Z.\} and Teale, \{Andrew M.\} and Tozer, \{David J.\} and Young, \{Robert J.\}",

year = "2006",

doi = "10.1039/b606334a",

language = "English",

pages = "3190--3192",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "30",

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T1 - The intramolecular beta-fluorine...ammonium interaction in 4- and 8-membered rings

AU - Gooseman, Natalie E. J.

AU - O'Hagan, David

AU - Slawin, Alexandra M. Z.

AU - Teale, Andrew M.

AU - Tozer, David J.

AU - Young, Robert J.

PY - 2006

Y1 - 2006

N2 - The structures of 3-fluoroazetidinium hydrochloride and 3-fluoro-1,5-diazacyclooctane hydrobromide are explored both by X-ray diffraction analysis and DFT calculations, and the conformations of these molecules are shown to be significantly influenced by the through space C-F center dot center dot center dot N+ interaction.

AB - The structures of 3-fluoroazetidinium hydrochloride and 3-fluoro-1,5-diazacyclooctane hydrobromide are explored both by X-ray diffraction analysis and DFT calculations, and the conformations of these molecules are shown to be significantly influenced by the through space C-F center dot center dot center dot N+ interaction.

KW - FLUORINE

UR - https://www.scopus.com/pages/publications/33746410059

U2 - 10.1039/b606334a

DO - 10.1039/b606334a

M3 - Article

SN - 1359-7345

SP - 3190

EP - 3192

JO - Chemical Communications

JF - Chemical Communications

IS - 30

ER -

The intramolecular beta-fluorine...ammonium interaction in 4- and 8-membered rings

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