The intramolecular beta-fluorine...ammonium interaction in 4- and 8-membered rings

Natalie E. J. Gooseman, David O'Hagan, Alexandra M. Z. Slawin, Andrew M. Teale, David J. Tozer, Robert J. Young

Research output: Contribution to journalArticlepeer-review

Abstract

The structures of 3-fluoroazetidinium hydrochloride and 3-fluoro-1,5-diazacyclooctane hydrobromide are explored both by X-ray diffraction analysis and DFT calculations, and the conformations of these molecules are shown to be significantly influenced by the through space C-F center dot center dot center dot N+ interaction.

Original languageEnglish
Pages (from-to)3190-3192
Number of pages3
JournalChemical Communications
Issue number30
DOIs
Publication statusPublished - 2006

Keywords

  • FLUORINE

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