The intercalation compound Li(Mn0.9Co0.1)O2 as a positive electrode for rechargeable lithium batteries

AR Armstrong; R Gitzendanner; AD Robertson; Peter George Bruce

The intercalation compound Li(Mn_0.9Co_0.1)O₂ as a positive electrode for rechargeable lithium batteries

AR Armstrong, R Gitzendanner, AD Robertson, Peter George Bruce

Research output: Other contribution

84 Citations (Scopus)

Abstract

By replacing only 10% of the Mn by Co in the layered lithium intercalation compound LiMnO2 the amount of lithium that can be removed and reinserted is increased by 50% corresponding to an increase in the ability to store charge from 130 to 200 mA h g(-1) at 100 mu A cm(-2) and rendering this low cost/toxicity material of potential interest as a positive electrode in rechargeable lithium batteries; furthermore the cooperative Jahn-Teller distortion due to localised high spin Mn3+(3d(4)) in LiMnO2 appears to be suppressed for Li-x(Mn0.9Co0.1)O-2; x < 0.9 (80% Mn3+ assuming Co3+).

Original language	English
Publication status	Published - 7 Sept 1998

Keywords

LIMN2O4
LIMNO2
POWER

Cite this

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title = "The intercalation compound Li(Mn0.9Co0.1)O2 as a positive electrode for rechargeable lithium batteries",

abstract = "By replacing only 10% of the Mn by Co in the layered lithium intercalation compound LiMnO2 the amount of lithium that can be removed and reinserted is increased by 50% corresponding to an increase in the ability to store charge from 130 to 200 mA h g(-1) at 100 mu A cm(-2) and rendering this low cost/toxicity material of potential interest as a positive electrode in rechargeable lithium batteries; furthermore the cooperative Jahn-Teller distortion due to localised high spin Mn3+(3d(4)) in LiMnO2 appears to be suppressed for Li-x(Mn0.9Co0.1)O-2; x < 0.9 (80% Mn3+ assuming Co3+).",

keywords = "LIMN2O4, LIMNO2, POWER",

author = "AR Armstrong and R Gitzendanner and AD Robertson and Bruce, {Peter George}",

note = "Chem Commun",

year = "1998",

month = sep,

day = "7",

language = "English",

type = "Other",

}

TY - GEN

T1 - The intercalation compound Li(Mn0.9Co0.1)O2 as a positive electrode for rechargeable lithium batteries

AU - Armstrong, AR

AU - Gitzendanner, R

AU - Robertson, AD

AU - Bruce, Peter George

N1 - Chem Commun

PY - 1998/9/7

Y1 - 1998/9/7

N2 - By replacing only 10% of the Mn by Co in the layered lithium intercalation compound LiMnO2 the amount of lithium that can be removed and reinserted is increased by 50% corresponding to an increase in the ability to store charge from 130 to 200 mA h g(-1) at 100 mu A cm(-2) and rendering this low cost/toxicity material of potential interest as a positive electrode in rechargeable lithium batteries; furthermore the cooperative Jahn-Teller distortion due to localised high spin Mn3+(3d(4)) in LiMnO2 appears to be suppressed for Li-x(Mn0.9Co0.1)O-2; x < 0.9 (80% Mn3+ assuming Co3+).

AB - By replacing only 10% of the Mn by Co in the layered lithium intercalation compound LiMnO2 the amount of lithium that can be removed and reinserted is increased by 50% corresponding to an increase in the ability to store charge from 130 to 200 mA h g(-1) at 100 mu A cm(-2) and rendering this low cost/toxicity material of potential interest as a positive electrode in rechargeable lithium batteries; furthermore the cooperative Jahn-Teller distortion due to localised high spin Mn3+(3d(4)) in LiMnO2 appears to be suppressed for Li-x(Mn0.9Co0.1)O-2; x < 0.9 (80% Mn3+ assuming Co3+).

KW - LIMN2O4

KW - LIMNO2

KW - POWER

UR - http://www.scopus.com/inward/record.url?scp=21844474806&partnerID=8YFLogxK

M3 - Other contribution

ER -

The intercalation compound Li(Mn_0.9Co_0.1)O₂ as a positive electrode for rechargeable lithium batteries

Abstract

Keywords

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