The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (±)-erythro- and (±)-threo-9,10-difluorostearic acids.

M Petty; M Pearson; David O'Hagan

doi:10.1039/b202891c

The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (±)-erythro- and (±)-threo-9,10-difluorostearic acids.

M Petty, M Pearson, David O'Hagan

Research output: Contribution to journal › Article › peer-review

Abstract

(+/-)-Erythro-and(+/-)-threo-9,10-difluorostearic acids which differ only by a stereogenic interconversion of a single C-F bond, have significantly different conformational stabilities.

Original language	English
Pages (from-to)	1226-1227
Number of pages	2
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/b202891c
Publication status	Published - 2002

Keywords

1,2-DIFLUOROETHANE

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10.1039/b202891c

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title = "The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (±)-erythro- and (±)-threo-9,10-difluorostearic acids.",

abstract = "(+/-)-Erythro-and(+/-)-threo-9,10-difluorostearic acids which differ only by a stereogenic interconversion of a single C-F bond, have significantly different conformational stabilities.",

keywords = "1,2-DIFLUOROETHANE",

author = "M Petty and M Pearson and David O'Hagan",

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doi = "10.1039/b202891c",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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AU - Pearson, M

AU - O'Hagan, David

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AB - (+/-)-Erythro-and(+/-)-threo-9,10-difluorostearic acids which differ only by a stereogenic interconversion of a single C-F bond, have significantly different conformational stabilities.

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U2 - 10.1039/b202891c

DO - 10.1039/b202891c

M3 - Article

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SP - 1226

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JO - Chemical Communications

JF - Chemical Communications

ER -

The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (±)-erythro- and (±)-threo-9,10-difluorostearic acids.

Abstract

Keywords

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