The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (±)-erythro- and (±)-threo-9,10-difluorostearic acids.

M Petty, M Pearson, David O'Hagan

Research output: Contribution to journalArticlepeer-review

58 Citations (Scopus)

Abstract

(+/-)-Erythro-and(+/-)-threo-9,10-difluorostearic acids which differ only by a stereogenic interconversion of a single C-F bond, have significantly different conformational stabilities.

Original languageEnglish
Pages (from-to)1226-1227
Number of pages2
JournalChemical Communications
DOIs
Publication statusPublished - 2002

Keywords

  • 1,2-DIFLUOROETHANE

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