Abstract
The first large pore ( free diameter >7 angstrom) metal phosphonates have been prepared as divalent metal N,N'-piperazinebis( methylenephosphonate)s that possess pores greater than ca. 10 angstrom in free diameter, are stable up to 400 degrees C and offer a route to chiral adsorbents and catalysts.
| Original language | English |
|---|---|
| Pages (from-to) | 3305-3307 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 2006 |
| Issue number | 31 |
| DOIs | |
| Publication status | Published - Jan 2006 |
Keywords
- LINED UNIDIMENSIONAL CHANNELS
- ALUMINUM METHYLPHOSPHONATE
- CRYSTAL-STRUCTURES
- ORGANIC FRAMEWORK
- ALMEPO-ALPHA
- ADSORPTION
- INCLUSION
- CAVITIES
- POLYMER
- DESIGN
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