The first route to large pore metal phosphonates

J A Groves, S R Miller, S J Warrender, C A Mellot-Draznieks, Philip Lightfoot, Paul Anthony Wright

Research output: Contribution to journalArticlepeer-review

117 Citations (Scopus)

Abstract

The first large pore ( free diameter >7 angstrom) metal phosphonates have been prepared as divalent metal N,N'-piperazinebis( methylenephosphonate)s that possess pores greater than ca. 10 angstrom in free diameter, are stable up to 400 degrees C and offer a route to chiral adsorbents and catalysts.

Original languageEnglish
Pages (from-to)3305-3307
Number of pages3
JournalChemical Communications
Volume2006
Issue number31
DOIs
Publication statusPublished - Jan 2006

Keywords

  • LINED UNIDIMENSIONAL CHANNELS
  • ALUMINUM METHYLPHOSPHONATE
  • CRYSTAL-STRUCTURES
  • ORGANIC FRAMEWORK
  • ALMEPO-ALPHA
  • ADSORPTION
  • INCLUSION
  • CAVITIES
  • POLYMER
  • DESIGN

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