The efficiency of alkyl radical generation and hydrogen transfer from 1-alkylcyclohexa-2,5-diene-1-carboxylic acids

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Abstract

A novel EPR spectroscopic technique has been used to determine kinetic data for alkyl radical generation and hydrogen transfer from 1-alkylcyclohexa-2,5-diene-1-carboxylic acids; the implications of these data for preparative chain reactions of these reagents are inferred. (C) 1999 Elsevier Science Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)7019-7021
Number of pages3
JournalTetrahedron Letters
Volume40
Publication statusPublished - 17 Sept 1999

Keywords

  • chain reactions
  • carboxylic acids
  • radicals
  • kinetics
  • structure-activity
  • ELECTRON-SPIN-RESONANCE
  • RATE CONSTANTS
  • ESTERS

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