The effect of radical size and structure on the orientation of addition of perfluoroalkyl radicals to fluoro-alkenes

David S. Ashton; Anne F. Mackay; John M. Tedder; David C. Tipney; John C. Walton

doi:10.1039/C39730000496

The effect of radical size and structure on the orientation of addition of perfluoroalkyl radicals to fluoro-alkenes

David S. Ashton, Anne F. Mackay, John M. Tedder^*, David C. Tipney, John C. Walton

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The orientation of the addition of CF₃·, C ₂F₅·, n-C₃F₇·, n-C₄F₉·, n-C₇F₁₅·, n-C₇F₁₈·, and (CF₃) ₂CF· radicals to CFH=CH₂, CF₂=CH ₂, and CFH=CF₂ has been determined in the gas phase.

Original language	English
Pages (from-to)	496-497
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/C39730000496
Publication status	Published - 1 Jan 1973

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title = "The effect of radical size and structure on the orientation of addition of perfluoroalkyl radicals to fluoro-alkenes",

abstract = "The orientation of the addition of CF3·, C 2F5·, n-C3F7·, n-C4F9·, n-C7F15·, n-C7F18·, and (CF3) 2CF· radicals to CFH=CH2, CF2=CH 2, and CFH=CF2 has been determined in the gas phase.",

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AU - Ashton, David S.

AU - Mackay, Anne F.

AU - Tedder, John M.

AU - Tipney, David C.

AU - Walton, John C.

PY - 1973/1/1

Y1 - 1973/1/1

N2 - The orientation of the addition of CF3·, C 2F5·, n-C3F7·, n-C4F9·, n-C7F15·, n-C7F18·, and (CF3) 2CF· radicals to CFH=CH2, CF2=CH 2, and CFH=CF2 has been determined in the gas phase.

AB - The orientation of the addition of CF3·, C 2F5·, n-C3F7·, n-C4F9·, n-C7F15·, n-C7F18·, and (CF3) 2CF· radicals to CFH=CH2, CF2=CH 2, and CFH=CF2 has been determined in the gas phase.

UR - https://www.scopus.com/pages/publications/37049139392

U2 - 10.1039/C39730000496

DO - 10.1039/C39730000496

M3 - Article

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

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ER -

The effect of radical size and structure on the orientation of addition of perfluoroalkyl radicals to fluoro-alkenes

Abstract

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