THE CRYSTAL AND MOLECULAR-STRUCTURE OF TRIBENZYLSILANOL BY RIETVELD REFINEMENT OF POWDER X-RAY-DIFFRACTION DATA

P  LIGHTFOOT; C  GLIDEWELL; P G  BRUCE

THE CRYSTAL AND MOLECULAR-STRUCTURE OF TRIBENZYLSILANOL BY RIETVELD REFINEMENT OF POWDER X-RAY-DIFFRACTION DATA

P LIGHTFOOT, C GLIDEWELL, P G BRUCE

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal and molecular structure of tibenzylsilanol ((PhCH(2))(3)SiOH) has been refined by the Rietveld method from X-ray powder diffraction data collected with a conventional laboratory powder diffractometer. The compound is isostructural with tribenzylmethanol ((PhCH(2))(3)COH). The crystal consists of isolated molecules with approximate threefold molecular symmetry: there is no hydrogen bonding between the molecules.

Original language	English
Pages (from-to)	51-54
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	466
Issue number	1-2
Publication status	Published - 22 Feb 1994

Keywords

TRIBENZYLSILANOL
HYDROGEN BONDING
X-RAY POWDER DIFFRACTION
RIETVELD REFINEMENT
CRYSTAL STRUCTURE
ABINITIO DETERMINATION
ENTROPY

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title = "THE CRYSTAL AND MOLECULAR-STRUCTURE OF TRIBENZYLSILANOL BY RIETVELD REFINEMENT OF POWDER X-RAY-DIFFRACTION DATA",

abstract = "The crystal and molecular structure of tibenzylsilanol ((PhCH(2))(3)SiOH) has been refined by the Rietveld method from X-ray powder diffraction data collected with a conventional laboratory powder diffractometer. The compound is isostructural with tribenzylmethanol ((PhCH(2))(3)COH). The crystal consists of isolated molecules with approximate threefold molecular symmetry: there is no hydrogen bonding between the molecules.",

keywords = "TRIBENZYLSILANOL, HYDROGEN BONDING, X-RAY POWDER DIFFRACTION, RIETVELD REFINEMENT, CRYSTAL STRUCTURE, ABINITIO DETERMINATION, ENTROPY",

author = "P LIGHTFOOT and C GLIDEWELL and BRUCE, \{P G\}",

year = "1994",

month = feb,

day = "22",

language = "English",

volume = "466",

pages = "51--54",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1-2",

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T1 - THE CRYSTAL AND MOLECULAR-STRUCTURE OF TRIBENZYLSILANOL BY RIETVELD REFINEMENT OF POWDER X-RAY-DIFFRACTION DATA

AU - LIGHTFOOT, P

AU - GLIDEWELL, C

AU - BRUCE, P G

PY - 1994/2/22

Y1 - 1994/2/22

N2 - The crystal and molecular structure of tibenzylsilanol ((PhCH(2))(3)SiOH) has been refined by the Rietveld method from X-ray powder diffraction data collected with a conventional laboratory powder diffractometer. The compound is isostructural with tribenzylmethanol ((PhCH(2))(3)COH). The crystal consists of isolated molecules with approximate threefold molecular symmetry: there is no hydrogen bonding between the molecules.

AB - The crystal and molecular structure of tibenzylsilanol ((PhCH(2))(3)SiOH) has been refined by the Rietveld method from X-ray powder diffraction data collected with a conventional laboratory powder diffractometer. The compound is isostructural with tribenzylmethanol ((PhCH(2))(3)COH). The crystal consists of isolated molecules with approximate threefold molecular symmetry: there is no hydrogen bonding between the molecules.

KW - TRIBENZYLSILANOL

KW - HYDROGEN BONDING

KW - X-RAY POWDER DIFFRACTION

KW - RIETVELD REFINEMENT

KW - CRYSTAL STRUCTURE

KW - ABINITIO DETERMINATION

KW - ENTROPY

UR - https://www.scopus.com/pages/publications/0011574729

M3 - Article

SN - 0022-328X

VL - 466

SP - 51

EP - 54

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

THE CRYSTAL AND MOLECULAR-STRUCTURE OF TRIBENZYLSILANOL BY RIETVELD REFINEMENT OF POWDER X-RAY-DIFFRACTION DATA

Abstract

Keywords

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