The corrosion behavior of a sputtered micrograin film on Fe-5Cr-5Si alloy in H2-CO2-H2S mixture at 700 °C

L. L. Liu; W. B. Li; Q. Q. Guo; C. S. Ni; Y. Niu

doi:10.1016/j.corsci.2016.05.017

The corrosion behavior of a sputtered micrograin film on Fe-5Cr-5Si alloy in H₂-CO₂-H₂S mixture at 700 °C

L. L. Liu, W. B. Li, Q. Q. Guo, C. S. Ni, Y. Niu

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The corrosion behaviors of as-cast Fe-5Cr-5Si alloy with and without sputtered Fe-5Cr-5Si film in H₂-CO₂-H₂S mixture at 700 °C are studied. The corrosion scale forming on the as-cast alloy is non-protective and mainly composed of FeS outer layer and FeS + FeCr₂O₄ + Fe₂SiO₄ inner layer. However, a continuous Cr₂O₃ + SiO₂ layer which possesses favorable protectiveness forms at the coating/alloy interface for the coated alloy, even though FeS layer and FeS + FeCr₂O₄ + Fe₂SiO₄ mixed layer also form. The formation mechanism of the Cr₂O₃ + SiO₂ layer on the coated alloy is discussed thoroughly.

Original language	English
Pages (from-to)	446-453
Journal	Corrosion Science
Volume	111
Early online date	16 May 2016
DOIs	https://doi.org/10.1016/j.corsci.2016.05.017
Publication status	Published - Oct 2017

Keywords

A sputtered film
B SEM
B EPMA
C oxidation
C sulphidation
C selective oxidation

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10.1016/j.corsci.2016.05.017

Ni_2016_SputteredMicrograin_CorrSci_AM
© 2016 Published by Elsevier Ltd. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1016/j.corsci.2016.05.017
Accepted author manuscript, 1.38 MB

Cite this

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title = "The corrosion behavior of a sputtered micrograin film on Fe-5Cr-5Si alloy in H2-CO2-H2S mixture at 700 °C",

abstract = "The corrosion behaviors of as-cast Fe-5Cr-5Si alloy with and without sputtered Fe-5Cr-5Si film in H2-CO2-H2S mixture at 700 °C are studied. The corrosion scale forming on the as-cast alloy is non-protective and mainly composed of FeS outer layer and FeS + FeCr2O4 + Fe2SiO4 inner layer. However, a continuous Cr2O3 + SiO2 layer which possesses favorable protectiveness forms at the coating/alloy interface for the coated alloy, even though FeS layer and FeS + FeCr2O4 + Fe2SiO4 mixed layer also form. The formation mechanism of the Cr2O3 + SiO2 layer on the coated alloy is discussed thoroughly.",

keywords = "A sputtered film, B SEM, B EPMA, C oxidation, C sulphidation, C selective oxidation",

author = "Liu, \{L. L.\} and Li, \{W. B.\} and Guo, \{Q. Q.\} and Ni, \{C. S.\} and Y. Niu",

note = "Financial support from the NSFC (Projects NO. 59071129 \& 51501135) is acknowledged.",

year = "2017",

month = oct,

doi = "10.1016/j.corsci.2016.05.017",

language = "English",

volume = "111",

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journal = "Corrosion Science",

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T1 - The corrosion behavior of a sputtered micrograin film on Fe-5Cr-5Si alloy in H2-CO2-H2S mixture at 700 °C

AU - Liu, L. L.

AU - Li, W. B.

AU - Guo, Q. Q.

AU - Ni, C. S.

AU - Niu, Y.

N1 - Financial support from the NSFC (Projects NO. 59071129 & 51501135) is acknowledged.

PY - 2017/10

Y1 - 2017/10

N2 - The corrosion behaviors of as-cast Fe-5Cr-5Si alloy with and without sputtered Fe-5Cr-5Si film in H2-CO2-H2S mixture at 700 °C are studied. The corrosion scale forming on the as-cast alloy is non-protective and mainly composed of FeS outer layer and FeS + FeCr2O4 + Fe2SiO4 inner layer. However, a continuous Cr2O3 + SiO2 layer which possesses favorable protectiveness forms at the coating/alloy interface for the coated alloy, even though FeS layer and FeS + FeCr2O4 + Fe2SiO4 mixed layer also form. The formation mechanism of the Cr2O3 + SiO2 layer on the coated alloy is discussed thoroughly.

AB - The corrosion behaviors of as-cast Fe-5Cr-5Si alloy with and without sputtered Fe-5Cr-5Si film in H2-CO2-H2S mixture at 700 °C are studied. The corrosion scale forming on the as-cast alloy is non-protective and mainly composed of FeS outer layer and FeS + FeCr2O4 + Fe2SiO4 inner layer. However, a continuous Cr2O3 + SiO2 layer which possesses favorable protectiveness forms at the coating/alloy interface for the coated alloy, even though FeS layer and FeS + FeCr2O4 + Fe2SiO4 mixed layer also form. The formation mechanism of the Cr2O3 + SiO2 layer on the coated alloy is discussed thoroughly.

KW - A sputtered film

KW - B SEM

KW - B EPMA

KW - C oxidation

KW - C sulphidation

KW - C selective oxidation

UR - https://www.scopus.com/pages/publications/84971667567

U2 - 10.1016/j.corsci.2016.05.017

DO - 10.1016/j.corsci.2016.05.017

M3 - Article

SN - 0010-938X

VL - 111

SP - 446

EP - 453

JO - Corrosion Science

JF - Corrosion Science

ER -

The corrosion behavior of a sputtered micrograin film on Fe-5Cr-5Si alloy in H₂-CO₂-H₂S mixture at 700 °C

Abstract

Keywords

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