The Coordination Chemistry of 2-(diphenylamino)pyridine

John Derek Woollins; SM Aucott; Alexandra Martha Zoya Slawin

doi:10.1039/b003294h

The Coordination Chemistry of 2-(diphenylamino)pyridine

John Derek Woollins, SM Aucott, Alexandra Martha Zoya Slawin

Research output: Contribution to journal › Article › peer-review

109 Citations (Scopus)

Abstract

2-(Diphenylphosphinoamino)pyridine, dppap [Ph(2)PNHpy], and over 40 illustrative examples of its complexes have been prepared. Monodentate, bidentate and bridging co-ordination of the neutral (and bidentate deprotonated ligand) has been demonstrated in a range of palladium, platinum and gold complexes. Ten demonstrative examples have been characterised by single crystal X-ray diffraction. Ph(2)PNHpy exists as hydrogen-bonded dimer pairs; cis-[PtCl(Ph(2)PNHpy-P,N){Ph(2)PNHpy-P}]Cl packs in hydrogen-bonded infinite chains; cis-[Pt(Ph(2)PNpy-P,N)(2)] and cis-[Pd(Ph(2)PNpy-P,N)(2)] are isomorphous. The structures of cis-[Pd(Ph(2)PNHpy-P,N)(2)][BF4](2), [AuCl(Ph(2)PNHpy-P)], [Pt(C8H12OMe)(Ph(2)PNpy-P,N)]. H2O illustrating hydrogen-bonding, cis-[PtCl(Ph(2)PNHpy-P,N)(PMe3)]Cl, cis-[PtCl(Ph(2)PNpy-P,N)(PMe3)] and cis-[PtCl(Ph(2)PNHpy-P,N)(P(OPh)(3))]Cl are also reported.

Original language	English
Pages (from-to)	2559-2575
Number of pages	17
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	15
DOIs	https://doi.org/10.1039/b003294h
Publication status	Published - 2000

Keywords

RAY STRUCTURAL CHARACTERIZATION
MOLECULAR-STRUCTURE
COORDINATION CHEMISTRY
CRYSTAL-STRUCTURE
PLATINUM(II) COMPLEXES
PALLADIUM COMPLEXES
PHOSPHINE COMPLEXES
BINUCLEAR COMPLEXES
TRIDENTATE LIGAND
IRIDIUM COMPLEXES

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10.1039/b003294h

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title = "The Coordination Chemistry of 2-(diphenylamino)pyridine",

abstract = "2-(Diphenylphosphinoamino)pyridine, dppap [Ph(2)PNHpy], and over 40 illustrative examples of its complexes have been prepared. Monodentate, bidentate and bridging co-ordination of the neutral (and bidentate deprotonated ligand) has been demonstrated in a range of palladium, platinum and gold complexes. Ten demonstrative examples have been characterised by single crystal X-ray diffraction. Ph(2)PNHpy exists as hydrogen-bonded dimer pairs; cis-[PtCl(Ph(2)PNHpy-P,N){Ph(2)PNHpy-P}]Cl packs in hydrogen-bonded infinite chains; cis-[Pt(Ph(2)PNpy-P,N)(2)] and cis-[Pd(Ph(2)PNpy-P,N)(2)] are isomorphous. The structures of cis-[Pd(Ph(2)PNHpy-P,N)(2)][BF4](2), [AuCl(Ph(2)PNHpy-P)], [Pt(C8H12OMe)(Ph(2)PNpy-P,N)]. H2O illustrating hydrogen-bonding, cis-[PtCl(Ph(2)PNHpy-P,N)(PMe3)]Cl, cis-[PtCl(Ph(2)PNpy-P,N)(PMe3)] and cis-[PtCl(Ph(2)PNHpy-P,N)(P(OPh)(3))]Cl are also reported.",

keywords = "RAY STRUCTURAL CHARACTERIZATION, MOLECULAR-STRUCTURE, COORDINATION CHEMISTRY, CRYSTAL-STRUCTURE, PLATINUM(II) COMPLEXES, PALLADIUM COMPLEXES, PHOSPHINE COMPLEXES, BINUCLEAR COMPLEXES, TRIDENTATE LIGAND, IRIDIUM COMPLEXES",

author = "Woollins, {John Derek} and SM Aucott and Slawin, {Alexandra Martha Zoya}",

year = "2000",

doi = "10.1039/b003294h",

language = "English",

pages = "2559--2575",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "15",

}

TY - JOUR

T1 - The Coordination Chemistry of 2-(diphenylamino)pyridine

AU - Woollins, John Derek

AU - Aucott, SM

AU - Slawin, Alexandra Martha Zoya

PY - 2000

Y1 - 2000

N2 - 2-(Diphenylphosphinoamino)pyridine, dppap [Ph(2)PNHpy], and over 40 illustrative examples of its complexes have been prepared. Monodentate, bidentate and bridging co-ordination of the neutral (and bidentate deprotonated ligand) has been demonstrated in a range of palladium, platinum and gold complexes. Ten demonstrative examples have been characterised by single crystal X-ray diffraction. Ph(2)PNHpy exists as hydrogen-bonded dimer pairs; cis-[PtCl(Ph(2)PNHpy-P,N){Ph(2)PNHpy-P}]Cl packs in hydrogen-bonded infinite chains; cis-[Pt(Ph(2)PNpy-P,N)(2)] and cis-[Pd(Ph(2)PNpy-P,N)(2)] are isomorphous. The structures of cis-[Pd(Ph(2)PNHpy-P,N)(2)][BF4](2), [AuCl(Ph(2)PNHpy-P)], [Pt(C8H12OMe)(Ph(2)PNpy-P,N)]. H2O illustrating hydrogen-bonding, cis-[PtCl(Ph(2)PNHpy-P,N)(PMe3)]Cl, cis-[PtCl(Ph(2)PNpy-P,N)(PMe3)] and cis-[PtCl(Ph(2)PNHpy-P,N)(P(OPh)(3))]Cl are also reported.

AB - 2-(Diphenylphosphinoamino)pyridine, dppap [Ph(2)PNHpy], and over 40 illustrative examples of its complexes have been prepared. Monodentate, bidentate and bridging co-ordination of the neutral (and bidentate deprotonated ligand) has been demonstrated in a range of palladium, platinum and gold complexes. Ten demonstrative examples have been characterised by single crystal X-ray diffraction. Ph(2)PNHpy exists as hydrogen-bonded dimer pairs; cis-[PtCl(Ph(2)PNHpy-P,N){Ph(2)PNHpy-P}]Cl packs in hydrogen-bonded infinite chains; cis-[Pt(Ph(2)PNpy-P,N)(2)] and cis-[Pd(Ph(2)PNpy-P,N)(2)] are isomorphous. The structures of cis-[Pd(Ph(2)PNHpy-P,N)(2)][BF4](2), [AuCl(Ph(2)PNHpy-P)], [Pt(C8H12OMe)(Ph(2)PNpy-P,N)]. H2O illustrating hydrogen-bonding, cis-[PtCl(Ph(2)PNHpy-P,N)(PMe3)]Cl, cis-[PtCl(Ph(2)PNpy-P,N)(PMe3)] and cis-[PtCl(Ph(2)PNHpy-P,N)(P(OPh)(3))]Cl are also reported.

KW - RAY STRUCTURAL CHARACTERIZATION

KW - MOLECULAR-STRUCTURE

KW - COORDINATION CHEMISTRY

KW - CRYSTAL-STRUCTURE

KW - PLATINUM(II) COMPLEXES

KW - PALLADIUM COMPLEXES

KW - PHOSPHINE COMPLEXES

KW - BINUCLEAR COMPLEXES

KW - TRIDENTATE LIGAND

KW - IRIDIUM COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=0003052299&partnerID=8YFLogxK

U2 - 10.1039/b003294h

DO - 10.1039/b003294h

M3 - Article

SN - 1470-479X

SP - 2559

EP - 2575

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 15

ER -

The Coordination Chemistry of 2-(diphenylamino)pyridine

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Keywords

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