TY - JOUR
T1 - The Chemistry of (ECN)2 (E = S, Se) and Related Compounds
AU - Burchell, Colin James
AU - Aucott, Stephen Mark
AU - Robertson, Stuart Duncan
AU - Slawin, Alexandra Martha Zoya
AU - Woollins, John Derek
PY - 2004/4
Y1 - 2004/4
N2 - The psuedohalogens (ECN)(2) (E = S, Se) have been prepared by reaction of AgNCS with bromine and AgNCSe with iodine respectively. (SCN)(2) spontaneously polymerises to give polythiocyanogen a polymer of unknown structure with empirical formula (SCN)(x). A series of late transition metal complexes bearing the ambidentate psuedohalide ligands (ECN) (E = S, SO have been synthesised. In addition we have prepared a series of late transition metal complexes of the cyanodithioimidocarbonate ion [C2N2S2](2-) and the first transition metal complexes of the cyanodiselenocarbonate ion [C2N2Se2](2-).
AB - The psuedohalogens (ECN)(2) (E = S, Se) have been prepared by reaction of AgNCS with bromine and AgNCSe with iodine respectively. (SCN)(2) spontaneously polymerises to give polythiocyanogen a polymer of unknown structure with empirical formula (SCN)(x). A series of late transition metal complexes bearing the ambidentate psuedohalide ligands (ECN) (E = S, SO have been synthesised. In addition we have prepared a series of late transition metal complexes of the cyanodithioimidocarbonate ion [C2N2S2](2-) and the first transition metal complexes of the cyanodiselenocarbonate ion [C2N2Se2](2-).
KW - ambidentate
KW - bidentate
KW - complexes
KW - crystal structure
KW - pseudohalogens
KW - TRANSIENT (SCN)2
KW - THIOCYANOGEN
KW - SPECTRUM
UR - http://www.scopus.com/inward/record.url?scp=3042567342&partnerID=8YFLogxK
U2 - 10.1080/10426500490427619
DO - 10.1080/10426500490427619
M3 - Article
SN - 1042-6507
VL - 179
SP - 865
EP - 866
JO - Phosphorus, Sulfur, and Silicon and the Related Elements
JF - Phosphorus, Sulfur, and Silicon and the Related Elements
IS - 4-5
ER -