The carbonylation of methylacetate to acetic anhydride catalysed by [Cp*Rh(CO)2] in the absence of hydrogen

Andrew C. Marr; Philip Lightfoot; Evert J. Ditzel; Andrew D. Poole; Gary P. Schwarz; Douglas F. Foster; David J. Cole-Hamilton

doi:10.1016/S1387-7003(00)00157-X

The carbonylation of methylacetate to acetic anhydride catalysed by [Cp*Rh(CO)₂] in the absence of hydrogen

Andrew C. Marr
, Philip Lightfoot
, Evert J. Ditzel
, Andrew D. Poole
, Gary P. Schwarz
, Douglas F. Foster
, David J. Cole-Hamilton^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

[Cp°Rh(CO)₂] catalyses the carbonylation of methylacetate to acetic anhydride at 6.9 mol dm³ h^-1 in the absence of hydrogen; [Cp*RhI₂(CO)] which forms from it is also catalytically active giving rates of 1.2 mol dm³ h^-1 under the same conditions. (C) 2000 Elsevier Science S.A.

Original language	English
Pages (from-to)	617-619
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	3
Issue number	11
DOIs	https://doi.org/10.1016/S1387-7003(00)00157-X
Publication status	Published - 27 Nov 2000

Keywords

Acetic anhydride
Carbonylation
Methyl acetate
Pentamethylcyclopentadienyl
Rhodium
WGSR

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Cite this

@article{5dd45157fcea4ab0baa93e3d52637d79,

title = "The carbonylation of methylacetate to acetic anhydride catalysed by [Cp*Rh(CO)2] in the absence of hydrogen",

abstract = "[Cp°Rh(CO)2] catalyses the carbonylation of methylacetate to acetic anhydride at 6.9 mol dm3 h-1 in the absence of hydrogen; [Cp*RhI2(CO)] which forms from it is also catalytically active giving rates of 1.2 mol dm3 h-1 under the same conditions. (C) 2000 Elsevier Science S.A.",

keywords = "Acetic anhydride, Carbonylation, Methyl acetate, Pentamethylcyclopentadienyl, Rhodium, WGSR",

author = "Marr, \{Andrew C.\} and Philip Lightfoot and Ditzel, \{Evert J.\} and Poole, \{Andrew D.\} and Schwarz, \{Gary P.\} and Foster, \{Douglas F.\} and Cole-Hamilton, \{David J.\}",

year = "2000",

month = nov,

day = "27",

doi = "10.1016/S1387-7003(00)00157-X",

language = "English",

volume = "3",

pages = "617--619",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "11",

}

TY - JOUR

T1 - The carbonylation of methylacetate to acetic anhydride catalysed by [Cp*Rh(CO)2] in the absence of hydrogen

AU - Marr, Andrew C.

AU - Lightfoot, Philip

AU - Ditzel, Evert J.

AU - Poole, Andrew D.

AU - Schwarz, Gary P.

AU - Foster, Douglas F.

AU - Cole-Hamilton, David J.

PY - 2000/11/27

Y1 - 2000/11/27

N2 - [Cp°Rh(CO)2] catalyses the carbonylation of methylacetate to acetic anhydride at 6.9 mol dm3 h-1 in the absence of hydrogen; [Cp*RhI2(CO)] which forms from it is also catalytically active giving rates of 1.2 mol dm3 h-1 under the same conditions. (C) 2000 Elsevier Science S.A.

AB - [Cp°Rh(CO)2] catalyses the carbonylation of methylacetate to acetic anhydride at 6.9 mol dm3 h-1 in the absence of hydrogen; [Cp*RhI2(CO)] which forms from it is also catalytically active giving rates of 1.2 mol dm3 h-1 under the same conditions. (C) 2000 Elsevier Science S.A.

KW - Acetic anhydride

KW - Carbonylation

KW - Methyl acetate

KW - Pentamethylcyclopentadienyl

KW - Rhodium

KW - WGSR

UR - https://www.scopus.com/pages/publications/0033746395

U2 - 10.1016/S1387-7003(00)00157-X

DO - 10.1016/S1387-7003(00)00157-X

M3 - Article

AN - SCOPUS:0033746395

SN - 1387-7003

VL - 3

SP - 617

EP - 619

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 11

ER -