The carbonylation of methyl acetate to acetic anhydride catalysed by [Cp*Rh(CO)2] in the absence of hydrogen

AC Marr; Philip Lightfoot; EJ Ditzel; AD Poole; GP Schwarz; DF Foster; David John Cole-Hamilton

The carbonylation of methyl acetate to acetic anhydride catalysed by [Cp*Rh(CO)2] in the absence of hydrogen

AC Marr, Philip Lightfoot, EJ Ditzel, AD Poole, GP Schwarz, DF Foster, David John Cole-Hamilton

Research output: Other contribution

Abstract

[Cp * Rh(CO)(2)] catalyses the carbonylation of methylacetate to acetic anhydride at 6.9 mol dm(3) h(-1) in the absence of hydrogen; [Cp * RhI2(CO)] which forms from it is also catalytically active giving rates of 1.2 mol dm(3) h(-1) under the same conditions.

[GRAPHICS]

Original language	English
Volume	3
Publication status	Published - Nov 2000

Keywords

methyl acetate
carbonylation
acetic anhydride
rhodium
pentamethylcyclopentadienyl
WGSR
COMPLEXES
METHANOL
RHODIUM

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title = "The carbonylation of methyl acetate to acetic anhydride catalysed by [Cp*Rh(CO)2] in the absence of hydrogen",

abstract = "[Cp * Rh(CO)(2)] catalyses the carbonylation of methylacetate to acetic anhydride at 6.9 mol dm(3) h(-1) in the absence of hydrogen; [Cp * RhI2(CO)] which forms from it is also catalytically active giving rates of 1.2 mol dm(3) h(-1) under the same conditions.[GRAPHICS](C) 2000 Elsevier Science S.A. All rights reserved.",

keywords = "methyl acetate, carbonylation, acetic anhydride, rhodium, pentamethylcyclopentadienyl, WGSR, COMPLEXES, METHANOL, RHODIUM",

author = "AC Marr and Philip Lightfoot and EJ Ditzel and AD Poole and GP Schwarz and DF Foster and Cole-Hamilton, {David John}",

note = "Inorg Chem Commun",

year = "2000",

month = nov,

language = "English",

volume = "3",

type = "Other",

}

TY - GEN

T1 - The carbonylation of methyl acetate to acetic anhydride catalysed by [Cp*Rh(CO)2] in the absence of hydrogen

AU - Marr, AC

AU - Lightfoot, Philip

AU - Ditzel, EJ

AU - Poole, AD

AU - Schwarz, GP

AU - Foster, DF

AU - Cole-Hamilton, David John

N1 - Inorg Chem Commun

PY - 2000/11

Y1 - 2000/11

N2 - [Cp * Rh(CO)(2)] catalyses the carbonylation of methylacetate to acetic anhydride at 6.9 mol dm(3) h(-1) in the absence of hydrogen; [Cp * RhI2(CO)] which forms from it is also catalytically active giving rates of 1.2 mol dm(3) h(-1) under the same conditions.[GRAPHICS](C) 2000 Elsevier Science S.A. All rights reserved.

AB - [Cp * Rh(CO)(2)] catalyses the carbonylation of methylacetate to acetic anhydride at 6.9 mol dm(3) h(-1) in the absence of hydrogen; [Cp * RhI2(CO)] which forms from it is also catalytically active giving rates of 1.2 mol dm(3) h(-1) under the same conditions.[GRAPHICS](C) 2000 Elsevier Science S.A. All rights reserved.

KW - methyl acetate

KW - carbonylation

KW - acetic anhydride

KW - rhodium

KW - pentamethylcyclopentadienyl

KW - WGSR

KW - COMPLEXES

KW - METHANOL

KW - RHODIUM

M3 - Other contribution

VL - 3

ER -

The carbonylation of methyl acetate to acetic anhydride catalysed by [Cp*Rh(CO)2] in the absence of hydrogen

Abstract

Keywords

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