The capture of acetonitrile during a Bischler-Napieralski cyclisation reaction of an oxamide derivative

H  Heaney; K F  Shuhaibar; A M Z  Slawin

The capture of acetonitrile during a Bischler-Napieralski cyclisation reaction of an oxamide derivative

H Heaney, K F Shuhaibar, A M Z Slawin

Research output: Contribution to journal › Article › peer-review

Abstract

Attempts to extend Bischler-Napieralski reactions of oxamide derivatives to seven-membered ring analogues of 1,1'-bi-isoquinolinyl were problematic and although a 1,1'-bi-benzazepine was obtained in a low yield an imidazolidinone was isolated in high yield as a result of the capture of acetonitrile by a reactive intermediate. Copyright (C) 1996 Elsevier Science Ltd

Original language	English
Pages (from-to)	4275-4276
Number of pages	2
Journal	Tetrahedron Letters
Volume	37
Issue number	24
Publication status	Published - 10 Jun 1996

Keywords

PYROPHOSPHORYL CHLORIDE
VILSMEIER FORMYLATION
MECHANISM

Cite this

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title = "The capture of acetonitrile during a Bischler-Napieralski cyclisation reaction of an oxamide derivative",

abstract = "Attempts to extend Bischler-Napieralski reactions of oxamide derivatives to seven-membered ring analogues of 1,1'-bi-isoquinolinyl were problematic and although a 1,1'-bi-benzazepine was obtained in a low yield an imidazolidinone was isolated in high yield as a result of the capture of acetonitrile by a reactive intermediate. Copyright (C) 1996 Elsevier Science Ltd",

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AU - Heaney, H

AU - Shuhaibar, K F

AU - Slawin, A M Z

PY - 1996/6/10

Y1 - 1996/6/10

N2 - Attempts to extend Bischler-Napieralski reactions of oxamide derivatives to seven-membered ring analogues of 1,1'-bi-isoquinolinyl were problematic and although a 1,1'-bi-benzazepine was obtained in a low yield an imidazolidinone was isolated in high yield as a result of the capture of acetonitrile by a reactive intermediate. Copyright (C) 1996 Elsevier Science Ltd

AB - Attempts to extend Bischler-Napieralski reactions of oxamide derivatives to seven-membered ring analogues of 1,1'-bi-isoquinolinyl were problematic and although a 1,1'-bi-benzazepine was obtained in a low yield an imidazolidinone was isolated in high yield as a result of the capture of acetonitrile by a reactive intermediate. Copyright (C) 1996 Elsevier Science Ltd

KW - PYROPHOSPHORYL CHLORIDE

KW - VILSMEIER FORMYLATION

KW - MECHANISM

UR - https://www.scopus.com/pages/publications/0029943008

M3 - Article

SN - 0040-4039

VL - 37

SP - 4275

EP - 4276

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 24

ER -

The capture of acetonitrile during a Bischler-Napieralski cyclisation reaction of an oxamide derivative

Abstract

Keywords

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