The ADOR mechanism for the synthesis of new zeolites

P. Eliášová; M. Opanasenko; Paul Stewart Wheatley; M. Shamzhy; M. Mazur; P. Nachtigall; W.J. Roth; Russell Edward Morris; J. Čejka

doi:10.1039/c5cs00045a

The ADOR mechanism for the synthesis of new zeolites

P. Eliášová, M. Opanasenko, Paul Stewart Wheatley, M. Shamzhy, M. Mazur, P. Nachtigall, W.J. Roth, Russell Edward Morris, J. Čejka

Research output: Contribution to journal › Article › peer-review

Abstract

A novel methodology, called ADOR (assembly-disassembly-organisation-reassembly), for the synthesis of zeolites is reviewed here in detail. The ADOR mechanism stems from the fact that certain chemical weakness against a stimulus may be present in a zeolite framework, which can then be utilized for the preparation of new solids through successive manipulation of the material. In this review, we discuss the critical factors of germanosilicate zeolites required for application of the ADOR protocol and describe the mechanism of hydrolysis, organisation and condensation to form new zeolites starting from zeolite UTL. Last but not least, we discuss the potential of this methodology to form other zeolites and the prospects for future investigations.

Original language	English
Pages (from-to)	7177-7206
Number of pages	30
Journal	Chemical Society Reviews
Volume	44
Issue number	20
Early online date	6 May 2015
DOIs	https://doi.org/10.1039/c5cs00045a
Publication status	Published - 21 Oct 2015

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Morris_2015_CSR_ADOR_AM
Copyright 2015 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C5CS00045A
Accepted author manuscript, 3.49 MB

Nanoparticle: Nanoparticle Approaches to Zeolitic Catalysts
Morris, R. E. (PI)
EPSRC
15/01/14 → 2/08/15
Project: Standard
Assembly Disassembly Reassembly: Assembly disassembly reassembly - New routes to extended structures and their impact
Morris, R. E. (PI)
EPSRC
1/08/13 → 31/07/18
Project: Fellowship

Cite this

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title = "The ADOR mechanism for the synthesis of new zeolites",

abstract = "A novel methodology, called ADOR (assembly-disassembly-organisation-reassembly), for the synthesis of zeolites is reviewed here in detail. The ADOR mechanism stems from the fact that certain chemical weakness against a stimulus may be present in a zeolite framework, which can then be utilized for the preparation of new solids through successive manipulation of the material. In this review, we discuss the critical factors of germanosilicate zeolites required for application of the ADOR protocol and describe the mechanism of hydrolysis, organisation and condensation to form new zeolites starting from zeolite UTL. Last but not least, we discuss the potential of this methodology to form other zeolites and the prospects for future investigations.",

author = "P. Eli{\'a}{\v s}ov{\'a} and M. Opanasenko and Wheatley, {Paul Stewart} and M. Shamzhy and M. Mazur and P. Nachtigall and W.J. Roth and Morris, {Russell Edward} and J. {\v C}ejka",

note = "This work was supported by the Czech Science Foundation Grant No. P106/12/G015 (Centre of Excellence) and Grant No. 14-30898P (MS only). W.J.R acknowledges partial financial support provided by the National Science Centre Poland with a grant approved under No. DEC-2011/03/B/ST5/01551. R.E.M. thanks the Royal Society for provision of an industry fellowship and the E.P.S.R.C. for funding (EP/K025112/1 and EP/L014475/1).",

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doi = "10.1039/c5cs00045a",

language = "English",

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AU - Eliášová, P.

AU - Opanasenko, M.

AU - Wheatley, Paul Stewart

AU - Shamzhy, M.

AU - Mazur, M.

AU - Nachtigall, P.

AU - Roth, W.J.

AU - Morris, Russell Edward

AU - Čejka, J.

N1 - This work was supported by the Czech Science Foundation Grant No. P106/12/G015 (Centre of Excellence) and Grant No. 14-30898P (MS only). W.J.R acknowledges partial financial support provided by the National Science Centre Poland with a grant approved under No. DEC-2011/03/B/ST5/01551. R.E.M. thanks the Royal Society for provision of an industry fellowship and the E.P.S.R.C. for funding (EP/K025112/1 and EP/L014475/1).

PY - 2015/10/21

Y1 - 2015/10/21

N2 - A novel methodology, called ADOR (assembly-disassembly-organisation-reassembly), for the synthesis of zeolites is reviewed here in detail. The ADOR mechanism stems from the fact that certain chemical weakness against a stimulus may be present in a zeolite framework, which can then be utilized for the preparation of new solids through successive manipulation of the material. In this review, we discuss the critical factors of germanosilicate zeolites required for application of the ADOR protocol and describe the mechanism of hydrolysis, organisation and condensation to form new zeolites starting from zeolite UTL. Last but not least, we discuss the potential of this methodology to form other zeolites and the prospects for future investigations.

AB - A novel methodology, called ADOR (assembly-disassembly-organisation-reassembly), for the synthesis of zeolites is reviewed here in detail. The ADOR mechanism stems from the fact that certain chemical weakness against a stimulus may be present in a zeolite framework, which can then be utilized for the preparation of new solids through successive manipulation of the material. In this review, we discuss the critical factors of germanosilicate zeolites required for application of the ADOR protocol and describe the mechanism of hydrolysis, organisation and condensation to form new zeolites starting from zeolite UTL. Last but not least, we discuss the potential of this methodology to form other zeolites and the prospects for future investigations.

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JF - Chemical Society Reviews

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The ADOR mechanism for the synthesis of new zeolites

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Projects

Nanoparticle: Nanoparticle Approaches to Zeolitic Catalysts

Assembly Disassembly Reassembly: Assembly disassembly reassembly - New routes to extended structures and their impact

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