The addition of sulphur chloride pentafluoride to trifluoroethylene

H. W. Sidebottom; J. M. Tedder; J. C. Walton

doi:10.1039/C29700000253

The addition of sulphur chloride pentafluoride to trifluoroethylene

H. W. Sidebottom, J. M. Tedder^*, J. C. Walton

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The free radical addition of SF₅Cl to trifluoroethylene in the gas phase yields both adducts (a) SF₅CHFCF₂Cl and (b) SF₅CF₂CHFCl, the ratio a/b depending not only on temperature but also on the absolute concentration of SF₅Cl: these observations can be accounted for in terms of reversible addition of SF ₅ radicals.

Original language	English
Pages (from-to)	253-254
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/C29700000253
Publication status	Published - 1 Jan 1970

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title = "The addition of sulphur chloride pentafluoride to trifluoroethylene",

abstract = "The free radical addition of SF5Cl to trifluoroethylene in the gas phase yields both adducts (a) SF5CHFCF2Cl and (b) SF5CF2CHFCl, the ratio a/b depending not only on temperature but also on the absolute concentration of SF5Cl: these observations can be accounted for in terms of reversible addition of SF 5 radicals.",

author = "Sidebottom, {H. W.} and Tedder, {J. M.} and Walton, {J. C.}",

year = "1970",

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AU - Tedder, J. M.

AU - Walton, J. C.

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Y1 - 1970/1/1

N2 - The free radical addition of SF5Cl to trifluoroethylene in the gas phase yields both adducts (a) SF5CHFCF2Cl and (b) SF5CF2CHFCl, the ratio a/b depending not only on temperature but also on the absolute concentration of SF5Cl: these observations can be accounted for in terms of reversible addition of SF 5 radicals.

AB - The free radical addition of SF5Cl to trifluoroethylene in the gas phase yields both adducts (a) SF5CHFCF2Cl and (b) SF5CF2CHFCl, the ratio a/b depending not only on temperature but also on the absolute concentration of SF5Cl: these observations can be accounted for in terms of reversible addition of SF 5 radicals.

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The addition of sulphur chloride pentafluoride to trifluoroethylene

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