THE 1ST REACTION OF S5N6 - STRUCTURE OF A COMPLEX CONTAINING AN S2N3- LIGAND

P F  KELLY; A M Z  SLAWIN; D J  WILLIAMS; J D  WOOLLINS

doi:10.1002/anie.199206161

THE 1ST REACTION OF S5N6 - STRUCTURE OF A COMPLEX CONTAINING AN S2N3- LIGAND

P F KELLY, A M Z SLAWIN, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

A new pattern of S-N bond lengths is found in the anion of (PPh4)[PdCl2(S2N3)] (see structure shown), the product of the reaction of explosive S5N6 with (PPh4)2[Pd2Cl6]. The distances between sulfur and bridgehead N atoms average 1.604 angstrom and between sulfur and metal-coordinated N atoms 1.486 angstrom; the latter bond lengths are among the shortest known in M-S-N rings.

Original language	English
Pages (from-to)	616-618
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	31
Issue number	5
DOIs	https://doi.org/10.1002/anie.199206161
Publication status	Published - May 1992

Keywords

SULFUR NITROGEN LIGANDS
CRYSTAL-STRUCTURE

Access to Document

10.1002/anie.199206161

Cite this

@article{4063f574b55848128c54af608605dff1,

title = "THE 1ST REACTION OF S5N6 - STRUCTURE OF A COMPLEX CONTAINING AN S2N3- LIGAND",

abstract = "A new pattern of S-N bond lengths is found in the anion of (PPh4)[PdCl2(S2N3)] (see structure shown), the product of the reaction of explosive S5N6 with (PPh4)2[Pd2Cl6]. The distances between sulfur and bridgehead N atoms average 1.604 angstrom and between sulfur and metal-coordinated N atoms 1.486 angstrom; the latter bond lengths are among the shortest known in M-S-N rings.",

keywords = "SULFUR NITROGEN LIGANDS, CRYSTAL-STRUCTURE",

author = "KELLY, \{P F\} and SLAWIN, \{A M Z\} and WILLIAMS, \{D J\} and WOOLLINS, \{J D\}",

year = "1992",

month = may,

doi = "10.1002/anie.199206161",

language = "English",

volume = "31",

pages = "616--618",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "Wiley-VCH, Weinheim",

number = "5",

}

TY - JOUR

T1 - THE 1ST REACTION OF S5N6 - STRUCTURE OF A COMPLEX CONTAINING AN S2N3- LIGAND

AU - KELLY, P F

AU - SLAWIN, A M Z

AU - WILLIAMS, D J

AU - WOOLLINS, J D

PY - 1992/5

Y1 - 1992/5

N2 - A new pattern of S-N bond lengths is found in the anion of (PPh4)[PdCl2(S2N3)] (see structure shown), the product of the reaction of explosive S5N6 with (PPh4)2[Pd2Cl6]. The distances between sulfur and bridgehead N atoms average 1.604 angstrom and between sulfur and metal-coordinated N atoms 1.486 angstrom; the latter bond lengths are among the shortest known in M-S-N rings.

AB - A new pattern of S-N bond lengths is found in the anion of (PPh4)[PdCl2(S2N3)] (see structure shown), the product of the reaction of explosive S5N6 with (PPh4)2[Pd2Cl6]. The distances between sulfur and bridgehead N atoms average 1.604 angstrom and between sulfur and metal-coordinated N atoms 1.486 angstrom; the latter bond lengths are among the shortest known in M-S-N rings.

KW - SULFUR NITROGEN LIGANDS

KW - CRYSTAL-STRUCTURE

UR - https://www.scopus.com/pages/publications/33748231135

U2 - 10.1002/anie.199206161

DO - 10.1002/anie.199206161

M3 - Comment/debate

SN - 0570-0833

VL - 31

SP - 616

EP - 618

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 5

ER -

THE 1ST REACTION OF S5N6 - STRUCTURE OF A COMPLEX CONTAINING AN S2N3- LIGAND

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this