Abstract
A new pattern of S-N bond lengths is found in the anion of (PPh4)[PdCl2(S2N3)] (see structure shown), the product of the reaction of explosive S5N6 with (PPh4)2[Pd2Cl6]. The distances between sulfur and bridgehead N atoms average 1.604 angstrom and between sulfur and metal-coordinated N atoms 1.486 angstrom; the latter bond lengths are among the shortest known in M-S-N rings.
Original language | English |
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Pages (from-to) | 616-618 |
Number of pages | 3 |
Journal | Angewandte Chemie International Edition in English |
Volume | 31 |
Issue number | 5 |
DOIs |
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Publication status | Published - May 1992 |
Keywords
- SULFUR NITROGEN LIGANDS
- CRYSTAL-STRUCTURE