THE 1ST REACTION OF S5N6 - STRUCTURE OF A COMPLEX CONTAINING AN S2N3- LIGAND

P F KELLY, A M Z SLAWIN, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journalComment/debatepeer-review

Abstract

A new pattern of S-N bond lengths is found in the anion of (PPh4)[PdCl2(S2N3)] (see structure shown), the product of the reaction of explosive S5N6 with (PPh4)2[Pd2Cl6]. The distances between sulfur and bridgehead N atoms average 1.604 angstrom and between sulfur and metal-coordinated N atoms 1.486 angstrom; the latter bond lengths are among the shortest known in M-S-N rings.

Original languageEnglish
Pages (from-to)616-618
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume31
Issue number5
DOIs
Publication statusPublished - May 1992

Keywords

  • SULFUR NITROGEN LIGANDS
  • CRYSTAL-STRUCTURE

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