Tandem deuteration/hydrosilylation reactions catalyzed by a rhodium carbene complex under solvent-free conditions

Jonathan D. Egbert; Steven P. Nolan

doi:10.1039/c2cc17196a

Tandem deuteration/hydrosilylation reactions catalyzed by a rhodium carbene complex under solvent-free conditions

Jonathan D. Egbert, Steven P. Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The complex [Rh((IBu)-Bu-t)(2)HCl] has been shown to be an active catalyst in the hydrosilylation of carbonyl and imine complexes. This reactivity, combined with the previously reported H/D exchange catalyzed by these complexes allows for a one pot, two step reaction using a single catalyst for both H/D exchange and hydrosilylation. Using triethylsilane, [Rh((IBu)-Bu-t)(2)Cl] catalyst, and D-2 gas, deuterated silyl-ethers can be synthesized in an atom-economical, solvent-free reaction.

Original language	English
Pages (from-to)	2794-2796
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	22
DOIs	https://doi.org/10.1039/c2cc17196a
Publication status	Published - 2012

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10.1039/c2cc17196a

EPSRC - EP/J011053/1- LATE TRANSITION: Late Transition Metal Hydroxide in Homogeneous Catalysis
Nolan, S. P. (PI)
EPSRC
15/03/12 → 14/03/15
Project: Standard

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title = "Tandem deuteration/hydrosilylation reactions catalyzed by a rhodium carbene complex under solvent-free conditions",

abstract = "The complex [Rh((IBu)-Bu-t)(2)HCl] has been shown to be an active catalyst in the hydrosilylation of carbonyl and imine complexes. This reactivity, combined with the previously reported H/D exchange catalyzed by these complexes allows for a one pot, two step reaction using a single catalyst for both H/D exchange and hydrosilylation. Using triethylsilane, [Rh((IBu)-Bu-t)(2)Cl] catalyst, and D-2 gas, deuterated silyl-ethers can be synthesized in an atom-economical, solvent-free reaction.",

author = "Egbert, {Jonathan D.} and Nolan, {Steven P.}",

year = "2012",

doi = "10.1039/c2cc17196a",

language = "English",

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pages = "2794--2796",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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AU - Egbert, Jonathan D.

AU - Nolan, Steven P.

PY - 2012

Y1 - 2012

N2 - The complex [Rh((IBu)-Bu-t)(2)HCl] has been shown to be an active catalyst in the hydrosilylation of carbonyl and imine complexes. This reactivity, combined with the previously reported H/D exchange catalyzed by these complexes allows for a one pot, two step reaction using a single catalyst for both H/D exchange and hydrosilylation. Using triethylsilane, [Rh((IBu)-Bu-t)(2)Cl] catalyst, and D-2 gas, deuterated silyl-ethers can be synthesized in an atom-economical, solvent-free reaction.

AB - The complex [Rh((IBu)-Bu-t)(2)HCl] has been shown to be an active catalyst in the hydrosilylation of carbonyl and imine complexes. This reactivity, combined with the previously reported H/D exchange catalyzed by these complexes allows for a one pot, two step reaction using a single catalyst for both H/D exchange and hydrosilylation. Using triethylsilane, [Rh((IBu)-Bu-t)(2)Cl] catalyst, and D-2 gas, deuterated silyl-ethers can be synthesized in an atom-economical, solvent-free reaction.

U2 - 10.1039/c2cc17196a

DO - 10.1039/c2cc17196a

M3 - Article

SN - 1359-7345

VL - 48

SP - 2794

EP - 2796

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

Tandem deuteration/hydrosilylation reactions catalyzed by a rhodium carbene complex under solvent-free conditions

Abstract

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Projects

EPSRC - EP/J011053/1- LATE TRANSITION: Late Transition Metal Hydroxide in Homogeneous Catalysis

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