Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts

C E Hartmann; V Jurcik; Olivier Songis; Catherine S.J. Cazin

doi:10.1039/c2cc38145a

Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts

C E Hartmann, V Jurcik, Olivier Songis, Catherine S.J. Cazin

Research output: Contribution to journal › Article › peer-review

Abstract

[Pd(NHC)(PR3)] complexes were shown to be active catalysts in the
dehydrogenation of ammonia borane and the subsequent hydrogenation
of unsaturated compounds at very low catalyst loadings
(0.05 mol% for some substrates).

Original language	English
Pages (from-to)	1005
Number of pages	1007
Journal	Chemical Communications
Volume	49
Early online date	14 Dec 2012
DOIs	https://doi.org/10.1039/c2cc38145a
Publication status	Published - Dec 2012

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10.1039/c2cc38145a

Studies of homogeneous catalysts: Mechanistic studies of homogeneous catalysts
Cazin, C. S. J. (PI)
The Royal Society
6/03/11 → 5/02/12
Project: Standard
Synergistic Ligand Effects in Palladium: Synergistic Ligand Effects in Palladium Catalysis
Cazin, C. S. J. (PI)
EPSRC
13/11/09 → 12/11/10
Project: Standard

Cite this

@article{76db8677bdd54d94be472ed3535bfc56,

title = "Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts",

abstract = "[Pd(NHC)(PR3)] complexes were shown to be active catalysts in thedehydrogenation of ammonia borane and the subsequent hydrogenationof unsaturated compounds at very low catalyst loadings(0.05 mol% for some substrates).",

author = "Hartmann, {C E} and V Jurcik and Olivier Songis and Cazin, {Catherine S.J.}",

year = "2012",

month = dec,

doi = "10.1039/c2cc38145a",

language = "English",

volume = "49",

pages = "1005",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts

AU - Hartmann, C E

AU - Jurcik, V

AU - Songis, Olivier

AU - Cazin, Catherine S.J.

PY - 2012/12

Y1 - 2012/12

N2 - [Pd(NHC)(PR3)] complexes were shown to be active catalysts in thedehydrogenation of ammonia borane and the subsequent hydrogenationof unsaturated compounds at very low catalyst loadings(0.05 mol% for some substrates).

AB - [Pd(NHC)(PR3)] complexes were shown to be active catalysts in thedehydrogenation of ammonia borane and the subsequent hydrogenationof unsaturated compounds at very low catalyst loadings(0.05 mol% for some substrates).

U2 - 10.1039/c2cc38145a

DO - 10.1039/c2cc38145a

M3 - Article

SN - 1359-7345

VL - 49

SP - 1005

JO - Chemical Communications

JF - Chemical Communications

ER -

Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts

Abstract

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Projects

Studies of homogeneous catalysts: Mechanistic studies of homogeneous catalysts

Synergistic Ligand Effects in Palladium: Synergistic Ligand Effects in Palladium Catalysis

Cite this