Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis

Elham Askarizadeh; Sahar Bani Yaghoob; Davar M. Boghaei; Alexandra M. Z. Slawin; Jason B. Love

doi:10.1039/b923189g

Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis

Elham Askarizadeh, Sahar Bani Yaghoob, Davar M. Boghaei, Alexandra M. Z. Slawin, Jason B. Love

Research output: Contribution to journal › Article › peer-review

Abstract

By modifying the mouth of a macrocyclic dicobalt Pacman complex, it is possible to both isolate new bridging-superoxo and hydroxyl complexes and to tune the reactivity of this system towards catalytic four-electron reduction of dioxygen to water.

Original language	English
Pages (from-to)	710-712
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	5
DOIs	https://doi.org/10.1039/b923189g
Publication status	Published - 2010

Keywords

PORPHYRIN-CORROLE DYADS
O BOND ACTIVATION
HANGMAN PORPHYRINS
FUEL-CELLS
OXYGEN
REACTIVITY
WATER
O-2
ARCHITECTURES
COBALT(III)

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10.1039/b923189g

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title = "Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis",

abstract = "By modifying the mouth of a macrocyclic dicobalt Pacman complex, it is possible to both isolate new bridging-superoxo and hydroxyl complexes and to tune the reactivity of this system towards catalytic four-electron reduction of dioxygen to water.",

keywords = "PORPHYRIN-CORROLE DYADS, O BOND ACTIVATION, HANGMAN PORPHYRINS, FUEL-CELLS, OXYGEN, REACTIVITY, WATER, O-2, ARCHITECTURES, COBALT(III)",

author = "Elham Askarizadeh and Yaghoob, {Sahar Bani} and Boghaei, {Davar M.} and Slawin, {Alexandra M. Z.} and Love, {Jason B.}",

year = "2010",

doi = "10.1039/b923189g",

language = "English",

volume = "46",

pages = "710--712",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "5",

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TY - JOUR

T1 - Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis

AU - Askarizadeh, Elham

AU - Yaghoob, Sahar Bani

AU - Boghaei, Davar M.

AU - Slawin, Alexandra M. Z.

AU - Love, Jason B.

PY - 2010

Y1 - 2010

N2 - By modifying the mouth of a macrocyclic dicobalt Pacman complex, it is possible to both isolate new bridging-superoxo and hydroxyl complexes and to tune the reactivity of this system towards catalytic four-electron reduction of dioxygen to water.

AB - By modifying the mouth of a macrocyclic dicobalt Pacman complex, it is possible to both isolate new bridging-superoxo and hydroxyl complexes and to tune the reactivity of this system towards catalytic four-electron reduction of dioxygen to water.

KW - PORPHYRIN-CORROLE DYADS

KW - O BOND ACTIVATION

KW - HANGMAN PORPHYRINS

KW - FUEL-CELLS

KW - OXYGEN

KW - REACTIVITY

KW - WATER

KW - O-2

KW - ARCHITECTURES

KW - COBALT(III)

U2 - 10.1039/b923189g

DO - 10.1039/b923189g

M3 - Article

SN - 1359-7345

VL - 46

SP - 710

EP - 712

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis

Abstract

Keywords

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